Application of cyclic voltammetry for stoichiometry determination of Ni(II), Co(II), and Cd(II) complex compounds with polyaminopolycarboxylic acids

Abstract

The purpose of the authors' study was to examine the usefulness of cyclic voltammetry to the determination of a complex compound's stoichiometry.

Voltammetric behavior of a ferrocene derivative: A comparison using surface-confined and diffusion-controlled species

“…Cyclic voltammetry (CV) has become one of the most wide-spread and important electrochemical techniques. During the last ten years, several excellent laboratory experiments about CV have appeared in this Journal (1)(2)(3)(4)(5)(6)(7)(8)(9). The main focus of these experiments has been to familiarize the students with the basic features of the technique and to demonstrate its usefulness in probing the redox chemistry of freely diffusing solution species.…”

Multivariate Curve Resolution of Cyclic Voltammetric Data: Application to the Study of the Cadmium-Binding Properties of Glutathione

“…Secondary effects such as the influence of low ligand concentration on the shapes and potentials of LSV and CV signals have been addressed . Both LSV and CV are also used in the determination of complex stoichiometry through the (linear) dependence of the peak current ( I p ) on concentration of the electroactive substance …”

Using Cyclic Voltammetry and Molecular Modeling To Determine Substituent Effects in the One-Electron Reduction of Benzoquinones

“…Cyclic voltammetry (CV), one of the most versatile of these new techniques, is often the first experiment performed in an electrochemical study and is used extensively in organic chemistry, biochemistry, and inorganic chemistry (1). Several articles have appeared in this Journal addressing the theory and importance of CV in the undergraduate curriculum (2)(3)(4)(5)(6)(7)(8)(9)(10)(11).…”