“…“Rubbers” are a member of a class of polymers known as “elastomers”, i.e., polymers that are characterized by large strain, low-modulus extensibility, and instantaneous and complete recovery after removal of the load. After stretching and deformation, they can return to the original shape. − The rubber retains an exclusive place in modern technology, due to its exceptional strength and tack in the prevulcanized state, and advanced crack-growth resistance and excellent mechanical performance once vulcanized. , The vulcanization process by which rubber is heated with sulfur and other additives to create a chemically cross-linked network was invented in 1839 by Charles Goodyear. − The unaccelerated vulcanization procedure applied elemental sulfur at 8 parts per 100 parts of rubber (8 phr) and an essential temperature of 143 °C for 6 h. It is desirable to accelerate the rate of vulcanization to lower energy/resource consumption and reach higher productivity. , By adding a few parts of the organic accelerators, the vulcanization time was reduced massively . Further, cross-linking formed a 3-D network structure, mainly coming from single, bisulfide, and polysulfide bonds, the yield of which depended on the quantities and forms of the vulcanization reagents and additives, such as the rubber precursors, activators (ZnO), fatty acids, accelerators, and antioxidants …”