Application of quaternary ammonium salt as catalyst in the reaction of glycidyl methacrylate with CO2

Soluble polymeric catalysts containing benzyltrialkylammonium chloride moieties and styrene or N,N‐dimethylacrylamide as a polar unit were prepared by copolymerization of vinylbenzyl chloride and the corresponding monomer, and then quaternization of the chloromethyl group by trialkylamines. The addition reaction of glycidyl methacrylate and carbon dioxide proceeded effectively using these polymer‐supported quaternary ammonium salts. The catalytic activity was affected by the amount of vinylbenzyl chloride, type of reaction solvent, and the structure of trialkylammonium salt due to the balance between lipophilicity and steric hindrance of the pendant quaternary ammonium salt. A kinetic study was also carried out to better understand the reaction steps. Copyright © 2003 John Wiley & Sons, Ltd.

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Soluble polymer‐bound quaternary ammonium salts for the addition reaction of glycidyl methacrylate with carbon dioxide

Kim

Shin

Lee

et al. 2003

Polymers for Advanced Techs

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Synthesis of phenoxymethyl ethylene carbonate using quaternary ammonium salt catalysts grafted onto styrene-vinylbenzylchloride-montmorillonite support

Shin

Kim

et al. 2003

Korean J. Chem. Eng.

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Synthesis of cyclic carbonate from vinyl cyclohexene oxide and CO2 using ionic liquids as catalysts

et al. 2008

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Application of quaternary ammonium salt as catalyst in the reaction of glycidyl methacrylate with CO2

Cited by 6 publications

References 12 publications

Soluble polymer‐bound quaternary ammonium salts for the addition reaction of glycidyl methacrylate with carbon dioxide

Soluble polymer‐bound quaternary ammonium salts for the addition reaction of glycidyl methacrylate with carbon dioxide

Synthesis of phenoxymethyl ethylene carbonate using quaternary ammonium salt catalysts grafted onto styrene-vinylbenzylchloride-montmorillonite support

Synthesis of cyclic carbonate from vinyl cyclohexene oxide and CO2 using ionic liquids as catalysts

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