2002
DOI: 10.1016/s0003-2670(02)00598-6
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Application of the luminol chemiluminescence reaction for the determination of nine corticosteroids

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Cited by 23 publications
(13 citation statements)
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“…In previous papers, high pressure pumps have been used for delivering the CL reagents using the luminol reaction [27,28] for detection coupled with HPLC, however in this case, when peristaltic pumps were tested for the CL reagents transportation instead of high pressure pumps, we obtained a smoother baseline and a much quicker stabilization of it. Furthermore, the use of peristaltic pumps is recommended in order to avoid a possible damage of the detection cell in case of high pressure in the system.…”
Section: Configuration Of the Post-column CL Assemblymentioning
confidence: 87%
“…In previous papers, high pressure pumps have been used for delivering the CL reagents using the luminol reaction [27,28] for detection coupled with HPLC, however in this case, when peristaltic pumps were tested for the CL reagents transportation instead of high pressure pumps, we obtained a smoother baseline and a much quicker stabilization of it. Furthermore, the use of peristaltic pumps is recommended in order to avoid a possible damage of the detection cell in case of high pressure in the system.…”
Section: Configuration Of the Post-column CL Assemblymentioning
confidence: 87%
“…25 and Y = 33026X -625.6, respectively (Y was the relative CL intensity and the X was the concentration of uric acid (µM)). The detection limit of uric acid was 2.58 × 10 -10 M (3σ).…”
Section: Calibration Curve and Detection Limitmentioning
confidence: 99%
“…These results indicated that the dissolved oxygen played an important role in the reaction, which was in agreement with several reports. 9,[22][23][24][25][26][27][28] It is well known that the type of species has great effect on its CL intensity. Our experiments indicated that molecular species of uric acid enhanced CL intensity markedly.…”
Section: Possible Mechanism Of the Present CL Reactionmentioning
confidence: 99%
“…Soc. 898 source, 9 HPLC-chemiluminescence, [10][11][12][13] and finally flowinjection chemiluminescence method coupled with solvent extraction. 14 Separation-detection methods such as GC-MS and HPLC-MS methods are expensive and time-consuming procedures, whereas the other separation methods suffer from such disadvantages as large amounts of high purity organic solvents required, long equilibration, and derivatization treatment.…”
Section: Introductionmentioning
confidence: 99%