With the introduction of ρ-reversibility, the basic notion of reversible Markov chain has been relaxed by allowing a wider range of scenarios. Specifically, the reversibility properties are not just sought on the chain itself, but also on all the possible topology-preserving renamings of its state space. Such renamings, called Renaming Functions, exhibit many interesting properties which can be exploited in different contexts. Unfortunately, finding a renaming function for a Markov chain is a very computationally intensive task. Using a naive approach it could require to check for all the possible state space permutations, which is unfeasible for all but the most trivial chains. As a matter of fact, we prove that the corresponding decision problem is polynomially equivalent to Graph Isomorphism. Nevertheless, we introduce an algorithm that, exploiting some necessary conditions for ρ-reversibility, is able to efficiently prune the search space and then verify the remaining renaming candidates. The correctness of the method is theoretically demonstrated and its practical effectiveness is shown over a significant set of discrete and continuous ρ-reversible Markov chains.