1997
DOI: 10.1021/jp963348i
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Aqueous Gold Sols of Rod-Shaped Particles

Abstract: Aqueous dispersions of rodlike gold particles are obtained by electrodeposition in nanopores of anodized alumina attached to a conductive support followed by dissolution of the alumina and stabilization of the rods with poly(vinylpyrrolydon). The obtained sol of monodisperse gold rods is examined by electron microscopy and visible (VIS) and near-infrared (NIR) spectroscopy. In the VIS/NIR absorption spectra two absorption maxima are present. With increasing aspect ratio, the maximum around 520 nm shifts to sho… Show more

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Cited by 248 publications
(148 citation statements)
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“…4(b) is that corresponding to a crossed rod target with =15º. The positions and origins of the transverse and longitudinal peaks on the sample with =0º (the simple rod) are consistent with previously reported results [37][38][39][40][41][42], with a transverse resonance at ~520 nm being visible in when E is directed across the long axis of the rod, and a longitudinal resonance at 700 nm becomes visible when E is directed parallel to the long axis.…”
Section: Methodssupporting
confidence: 89%
“…4(b) is that corresponding to a crossed rod target with =15º. The positions and origins of the transverse and longitudinal peaks on the sample with =0º (the simple rod) are consistent with previously reported results [37][38][39][40][41][42], with a transverse resonance at ~520 nm being visible in when E is directed across the long axis of the rod, and a longitudinal resonance at 700 nm becomes visible when E is directed parallel to the long axis.…”
Section: Methodssupporting
confidence: 89%
“…Seed-mediated [41,308], plasmon-mediated [309], and template-based [310][311][312] growths of anisotropic NMs are popular techniques in solution-based processes. Electrochemical method also shows the possibility for synthesizing gold nanorods [102,313,314].…”
Section: Size-and Shape-controlled Synthesismentioning
confidence: 99%
“…Since then, a plethora of studies have dealt with the production and characterization of noble metal colloids in a wide range of sizes [2][3][4], and for a variety of applications, including catalysis [5], biolabelling [6], biosensing [7], optical switches [8], among others. Only recently, variations in nanoparticle shape have been recognized as having a strong impact on their properties, which has motivated the development of synthetical methods for the preparation of particles with various geometries, such as rods [9][10][11][12][13], wires [14][15][16], prisms [17][18][19][20][21], cubes [22][23][24] and other polyhedrons [25,26].…”
Section: Introductionmentioning
confidence: 99%