Aqueous immiscibility of cholinium chloride ionic liquid and Triton surfactants

Liquid–Liquid Equilibrium of Aqueous Two-Phase Systems Composed of Nonionic Surfactant (Triton X-100, Triton X-165, or Triton X-305) and Choline Chloride

“…This was not observed for the choline chloride-rich phase, where the amount of water showed little variation with increase of the TLL. The immiscibility of systems composed of Triton X-100 and choline chloride was also studied by Álvarez et al, whose results were in agreement with the present findings.…”

“…In order to promote the phase segregation, surfactants have been used together with polymers , or organic and inorganic − salts. These systems offer lower interfacial tension, lower costs, absence of toxicity or flammability (in most cases), and short phase segregation times. , Notably, the nonionic surfactants known as Triton X, especially Triton X-100, Triton X-102, and Triton X-114, have been extensively used to obtain ATPSs. ,,− …”

Choline dihydrogen phosphate-based deep eutectic solvent: A suitable bioplatform for lipase extraction

“…In general terms, the exponential four parameter-equation allows slightly lower deviations for both non-ionic surfactants. These results are in agreement with our previous observations in ABS composed of cholinium-based ionic liquids and non-ionic surfactants [37,38] thus demonstrated the suitability of this equations for describing DES-based ABS. The analysis of the immiscibility regions reveals the suitability of choline dihydrogen phosphate-based DES to act as salting-out agent in aqueous solutions of both surfactants.…”

“…The analysis of the immiscibility regions reveals the suitability of choline dihydrogen phosphate-based DES to act as salting-out agent in aqueous solutions of both surfactants. Actually, the biphasic region size is greater than that reported for other imidazolium and cholinium-based ionic liquids [38][39][40][41], and is similar to that reported for recent papers using ChDHP as phase promoter [37,41]. This fact is interesting as the inclusion of ethyleneglycol in the DES synthesis does not involve a reduction in the phase segregation capacity while lowering the cost of the process (due to the lower price of ethyleneglycol regarding ChDHP).…”

New Low-Toxicity Cholinium-Based Ionic Liquids with Perfluoroalkanoate Anions for Aqueous Biphasic System Implementation

“…The ability to implement an ABS with these ILs and PPG400 was investigated, and the resulting ABSs were successfully applied to the extraction and purification of immunoglobulin Y from egg yolk. In a recent work, Álvarez et al showed that it is possible to perform ABS using nonionic surfactants and a choline based salt. In this work, choline chloride was used to determine the respective ABS at different temperatures and, the higher the temperature the higher the immiscibility between the components.…”