Choline dihydrogen phosphate-based deep eutectic solvent: A suitable bioplatform for lipase extraction

Álvarez, María S.; Rivas, M.A.; Longo, María A.; Deive, Francisco J.; Rodríguez, Ana

doi:10.1016/j.seppur.2021.118525

Cited by 13 publications

(4 citation statements)

References 50 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Recent works include the generation of binodal curve for surfactant (Triton X-100)�ionic liquid ATPS with choline cation 16 and cholinium dihydrogen phosphate. 17 Also, the equilibrium studies with different nonionic surfactants Tergitol 15 23 and Triton X-114 24 have been reported. Researchers have reported the equilibrium data of micellar ATPSs with salts of sodium, 22 magnesium, 25 thiocyanate 26 to study the temperature effect.…”

Section: Introductionmentioning

confidence: 99%

“…The addition of salt to surfactant solutions imparts the phase separation at lower temperatures, enabling the system for the extraction application at lower temperatures. Recent works include the generation of binodal curve for surfactant (Triton X-100)ionic liquid ATPS with choline cation and cholinium dihydrogen phosphate . Also, the equilibrium studies with different nonionic surfactants Tergitol 15 and Triton X-114 have been reported.…”

Section: Introductionmentioning

confidence: 99%

“…This drives the hydrophobic solute to partition into the surfactant-rich top phase, while hydrophilic solute moves to the polymer/salt-rich bottom phase. The advantages of micellar ATPSs include decreased interfacial tension, zero flammability, and a low cost of the phase-forming component. , Micellar ATPSs offer a potential for the extraction of hydrophobic solutes and researchers have reported micellar ATPS for dye partitioning, enzyme extraction, extraction from culture broth, , metal ion extraction, intracellular pigments, fatty acids, and phycoerythrin . Polymer–salt/ polymer–polymer systems are mostly studied for ATPS application, and comparatively fewer studies on equilibrium relation are reported for surfactant-based ATPSs.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Liquid–Liquid Equilibrium Data of Various Micellar Aqueous Two-Phase Systems for the Extraction of Rhodamine B and Hexavalent Chromium

Boravelli,

Vir

2024

J. Chem. Eng. Data

View full text Add to dashboard Cite

Micellar aqueous two-phase systems (ATPSs) find prominent applications in the extraction of hydrophobic solutes owing to their low interfacial tension. In this study, we investigated the liquid–liquid equilibrium (298.15 T/K and 101.325 P/kPa) and phase-forming abilities of organic (trisodium-citrate dihydrate and potassium sodium tartrate tetrahydrate) and inorganic (ammonium sulfate and ammonium phosphate dibasic) salts with an amphiphilic surfactant, Triton X-100. The experimental binodal curves for four micellar ATPSs were determined employing the cloud point method, and tie-line compositions were calculated using the gravimetric approach. The experimentally determined equilibrium data were thermodynamically correlated using effective excluded volume theory. For tie-line data accuracy, the Othmer–Tobias and Bancroft equations were used, and the corresponding correlation coefficients were reported. The phase separation ability of organic and inorganic salts was analyzed by using the Hofmeister series. Furthermore, we explored the effectiveness of micellar ATPSs in extracting hazardous pollutants from the textile industry, Rhodamine B (RB) and Chromium(VI) (Cr6+). Extraction experiments showed RB partitioning almost entirely (%E ∼ 99%) into a surfactant-rich phase, and ammonium sulfate-based ATPSs offered the highest extraction for the Cr6+ metal ion (% E = 81%). This study showcases the cost-effective way for the extraction of harmful hydrophobic industrial pollutants.

show abstract

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Liquid–Liquid Equilibrium Data of Various Micellar Aqueous Two-Phase Systems for the Extraction of Rhodamine B and Hexavalent Chromium

Boravelli,

Vir

2024

J. Chem. Eng. Data

View full text Add to dashboard Cite

show abstract

“…A comprehensive review of DESs, fundamentals and applications can be found in the literature [ 3 , 4 ]. More recent applications include biomass pre-treatment [ 5 , 6 ], media for enzymatic hydrolysis [ 7 , 8 ], platform for lipase extraction [ 9 ], biodiesel production and purification [ 10 , 11 ], inhibiting shale hydration [ 12 ] and COVID-19 intervention [ 13 ]. In the specific area of solvent extraction, a few recent studies are worthy of review.…”

Section: Introductionmentioning

confidence: 99%

Evaluation of hybrid solvents featuring choline chloride-based deep eutectic solvents and ethanol as extractants for the liquid–liquid extraction of benzene from n-hexane: towards a green and sustainable paradigm

2021

View full text Add to dashboard Cite

Deep eutectic solvents (DESs) have high viscosities, but known to be mitigated by addition of suitable co-solvent. The effect of such co-solvent on the extraction efficiency of the hybrid solvent is hardly known. This study examined the effect of ethanol on three choline chloride-based DESs (glyceline, reline, and ethaline) by mixing each in turn with ethanol in various volume proportions. The hybrid solvents were evaluated for the extraction of benzene from n-hexane. Pseudo-ternary liquid–liquid equilibrium data were obtained using the refractive index method at 303 K and 1 atm for the systems, n-hexane (1) + benzene (2) + hybrid solvent (glyceline/ethanol, ethaline/ethanol, reline/ethanol) (3), and used to evaluate distribution coefficient (D) and selectivity (S). Furthermore, the physicochemical properties of the hybrid solvents were also determined. The results indicate increase in selectivity with increasing ethanol addition up to 50% and decrease with further addition. All hybrid solvents with 50% ethanol outperform sulfolane and are suitable replacement for same as green and sustainable extractant for aromatics from aliphatics. The glyceline + 50% ethanol emerged the overall best with 49.73% elevation in selectivity and 41.15% reduction in viscosity relative to the neat glyceline. The finding of this study is expected to fillip the drive for paradigm shift in petrochemical industries.

show abstract

Deep eutectic solvents-based three-phase partitioning for tomato peroxidase purification: A promising method for substituting t-butanol

2022

View full text Add to dashboard Cite

Choline dihydrogen phosphate-based deep eutectic solvent: A suitable bioplatform for lipase extraction

Cited by 13 publications

References 50 publications

Liquid–Liquid Equilibrium Data of Various Micellar Aqueous Two-Phase Systems for the Extraction of Rhodamine B and Hexavalent Chromium

Liquid–Liquid Equilibrium Data of Various Micellar Aqueous Two-Phase Systems for the Extraction of Rhodamine B and Hexavalent Chromium

Evaluation of hybrid solvents featuring choline chloride-based deep eutectic solvents and ethanol as extractants for the liquid–liquid extraction of benzene from n-hexane: towards a green and sustainable paradigm

Deep eutectic solvents-based three-phase partitioning for tomato peroxidase purification: A promising method for substituting t-butanol

Contact Info

Product

Resources

About