Nanofluids
have emerged as an important working fluid for various
heat transfer and thermal energy transportation demands thanks to
its promising thermal conductivity. While, poor static stability brought
by segregation of nanoparticle heavily hinders its wide practical
utilization. In this work, a novel “one-pot one-step”
strategy was realized to generate a superior stable nanofluid which
can stand uneventfully for at least 2 months without observation of
any sedimentation with tetrabutyl titanate as a TiO2 precursor
in glycerol/chlorine chloride deep eutectic solvents. Mechanism study
reveals that the good stability of this nanofluid is mainly attributed
to in situ formation protocol for which the inherent
aggregation of TiO2 can be theoretically avoided. Meanwhile,
thermophysical properties, such as viscosity, thermal conductivity,
and rheological behavior, were comprehensively studied, which indicates
that the obtained nanofluids exhibit a non-Newtonian shear thinning
fluid behavior with a thermal conductivity enhancement ratio up to
9.0%. More importantly, photothermal conversion efficiency of the
nanofluid could reach 51.2%, and the efficiency enhancement is 181.9%
over the pristine deep eutectic solvents. This work paves a novel
avenue for fabricating nanofluids with super static stability and
gives a supplementary idea for “one-step” nanofluids
preparation process.