“…Typical encountered minerals in tailings are arsenopyrite (FeAsS), scorodite, (FeAsO 4 ⋅2H 2 O) and arsenian pyrite (As‐rich FeS 2 ) (Wang and Mulligan, 2006; Corriveau et al, 2011). In gold tailings, metals (e.g., Fe, Al, Mn, Cu, Pb, and Zn) can also be associated with As, as well as with clay minerals and oxyanions (e.g., sulfates, phosphates, and carbonates) (Wang and Mulligan, 2006; Hare et al, 2018). Generally, As species from the oxidation of these minerals are predominantly As(V) and, in minor amounts, As(−I) (Campbell and Nordstrom, 2014; DeSisto et al, 2017).…”