As-NQR Study of La Substitution Effect on the Interplay between Gap Formation and Structural Modulation in

Saiki, Takuo; Matsumura, Masatoshi; Kato, Hidemi; Nishioka, Takashi; Sasakawa, Tetsuya; Takabatake, T.

doi:10.1016/j.jmmm.2006.10.092

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2016

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“…The arsenide CeRhAs has been substituted only with small amounts of lanthanum up to a maximum concentration of Ce 0.95 La 0.05 RhAs [221,222,245]. These samples were studied by high-resolution resonance-photoemission spectroscopy in order to explain the collapse of the energy gap in the Kondo semiconducting state of CeRhAs as a consequence of cerium-by-lanthanum substitution.…”

Section: Solid Solutionsmentioning

confidence: 99%

Cerium intermetallics with TiNiSi-type structure

Janka

Niehaus

Pöttgen

et al. 2016

Zeitschrift Für Naturforschung B

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Intermetallic compounds with the equiatomic composition CeTX that crystallize with the orthorhombic TiNiSi-type structure can be synthesized with electronrich transition metals (T) and X = Zn, Al, Ga, Si, Ge, Sn, As, Sb, and Bi. The present review focusses on the crystal chemistry and chemical bonding of these CeTX phases and on their physical properties, 119 Sn and 121 Sb Mössbauer spectra, high-pressure effects, hydrogenation reactions and the formation of solid solutions in order to elucidate structure-property relationships. This paper is the final one of a series of four reviews on equiatomic intermetallic cerium compounds [Part I

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Section: Solid Solutionsmentioning

confidence: 99%