Bulk metallic glasses--formed by supercooling the liquid state of certain metallic alloys--have potentially superior mechanical properties to crystalline materials. Here, we report a Co(43)Fe(20)Ta(5.5)B(31.5) glassy alloy exhibiting ultrahigh fracture strength of 5,185 MPa, high Young's modulus of 268 GPa, high specific strength of 6.0 x 10(5) Nm kg(-1) and high specific Young's modulus of 31 x 10(6) Nm kg(-1). The strength, specific strength and specific Young's modulus are higher than previous values reported for any bulk crystalline or glassy alloys. Excellent formability is manifested by large tensile elongation of 1,400% and large reduction ratio in thickness above 90% in the supercooled liquid region. The ultrahigh-strength alloy also exhibited soft magnetic properties with extremely high permeability of 550,000. This alloy is promising as a new ultrahigh-strength material with good deformability and soft magnetic properties.
We synthesized freestanding bulk three-dimensional nanoporous Si using dealloying in a metallic melt, a top-down process. Using this nanoporous Si, we fabricated negative electrodes with high lithium capacity, nearing their theoretical limits, and greatly extended cycle lifetimes, considerably improving the battery performance compared with those using electrodes made from silicon nanoparticles. By operating the electrodes below the accommodation volume limit of their pores, we prolonged their cycle lifetime.
We make the first report that a metallic pyrochlore oxide,
Cd2Re2O7, exhibits type II superconductivity at
1.1 K. The pyrochlore oxide is known to be a geometrically frustrated
system, which includes a tetrahedral network of magnetic ions. A
large number of compounds are classified in the family of pyrochlore
oxides, and these compounds exhibit a wide variety of physical
properties ranging from insulator through semiconductor and from bad
metal to good metal. Until now, however, no superconductivity has
been reported for frustrated pyrochlore oxides. The bulk
superconductivity of this compound is confirmed by measurements of
the resistivity and the alternating-current magnetic susceptibility.
The upper critical field
Hc2, which is extrapolated to 0 K, is estimated as about
0.8 T, using the resistivity measurements under an applied field.
The plot of Hc2 versus T indicates that the Cooper pairs
are composed of rather heavy quasiparticles. This fact suggests
that frustrated heavy electrons become superconducting in this
compound.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.