Aspects of the interaction of pectin-coated Ag nanoparticles with methylene blue with regard to photodynamic applications

Hileuskaya, Kseniya; Ihnatsyeu-Kachan, Aliaksei; Kraskouski, Aliaksandr; Saichuk, Anastasiia; Hileuskaya, Aliaksandra; Nikalaichuk, V. V.; Kulikouskaya, Viktoryia; Kim, Sehoon

doi:10.1016/j.mtcomm.2023.105597

Cited by 3 publications

(2 citation statements)

References 66 publications

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“…The most common method of producing 1 O 2 relies upon photosensitizers that promote energy transfer and formation of 1 O 2 from the excited triplet state ( 3 O 2 ) upon exposure to light [9] . Frequently used photosensitizers are organic dyes such as methylene blue and rose red [10–11] . These organic dyes commonly aggregate at higher concentrations, and prolonged light exposure can result in fading and reduction of sensitization capability [12–13] .…”

Section: Introductionmentioning

confidence: 99%

Visible Light and Microwave‐Mediated Rapid Trapping and Release of Singlet Oxygen Using a Coordination Polymer

Deng

Chen

et al. 2023

Angew Chem Int Ed

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Due to its high reactivity and oxidative strength, singlet oxygen (1O2) is used in a variety of fields including organic synthesis, biomedicine, photodynamic therapy and materials science. Despite its importance, the controlled trapping and release of 1O2 is extremely challenging. Herein, we describe a one‐dimensional coordination polymer, CP1, which upon irradiation with visible light, transforms 3O2 (triplet oxygen) to 1O2. CP1 consists of CdII centers bridged by 9,10‐bis((E)‐2‐(pyridin‐4‐yl)vinyl)anthracene ligands which undergo a [4+2] cycloaddition reaction with 1O2, resulting in the generation of CP1−1O2. Using microwave irradiation, CP1−1O2 displays efficient release of 1O2, over a period of 30 s. In addition, CP1 exhibits enhanced fluorescence and has an oxygen detection limit of 97.4 ppm. Theoretical calculations reveal that the fluorescence behaviour is dominated by unique through‐space conjugation. In addition to describing a highly efficient approach for the trapping and controlled release of 1O2, using coordination polymers, this work also provides encouragement for the development of efficient fluorescent oxygen sensors.

show abstract

Section: Introductionmentioning

confidence: 99%

Visible Light and Microwave‐Mediated Rapid Trapping and Release of Singlet Oxygen Using a Coordination Polymer

Deng

Chen

et al. 2023

Angew Chem Int Ed

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show abstract

“…[9] Frequently used photosensitizers are organic dyes such as methylene blue and rose red. [10][11] These organic dyes commonly aggregate at higher concentrations, and prolonged light exposure can result in fading and reduction of sensitization capability. [12][13] In recent years, anthracene and its derivatives have been shown to undergo [4+2] cycloaddition reactions with 1 O 2 to form endoperoxides.…”

Section: Introductionmentioning

confidence: 99%

Visible Light and Microwave‐Mediated Rapid Trapping and Release of Singlet Oxygen Using a Coordination Polymer

Deng

Chen

et al. 2023

Angewandte Chemie

View full text Add to dashboard Cite

Due to its high reactivity and oxidative strength, singlet oxygen ( 1 O 2 ) is used in a variety of fields including organic synthesis, biomedicine, photodynamic therapy and materials science. Despite its importance, the controlled trapping and release of 1 O 2 is extremely challenging. Herein, we describe a onedimensional coordination polymer, CP1, which upon irradiation with visible light, transforms 3 O 2 (triplet oxygen) to 1 O 2 . CP1 consists of Cd II centers bridged by 9,10-bis((E)-2-(pyridin-4-yl)vinyl)anthracene ligands which undergo a [4+2] cycloaddition reaction with 1 O 2 , resulting in the generation of CP1À 1 O 2 . Using microwave irradiation, CP1À 1 O 2 displays efficient release of 1 O 2 , over a period of 30 s. In addition, CP1 exhibits enhanced fluorescence and has an oxygen detection limit of 97.4 ppm. Theoretical calculations reveal that the fluorescence behaviour is dominated by unique throughspace conjugation. In addition to describing a highly efficient approach for the trapping and controlled release of 1 O 2 , using coordination polymers, this work also provides encouragement for the development of efficient fluorescent oxygen sensors.

show abstract

New Insights into Chitosan-Ag Nanocomposites Synthesis: Physicochemical Aspects of Formation, Structure-Bioactivity Relationship and Mechanism of Antioxidant Activity

Hileuskaya,

Kraskouski,

Ihnatsyeu-Kachan

et al. 2024

Preprint

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Aspects of the interaction of pectin-coated Ag nanoparticles with methylene blue with regard to photodynamic applications

Cited by 3 publications

References 66 publications

Visible Light and Microwave‐Mediated Rapid Trapping and Release of Singlet Oxygen Using a Coordination Polymer

Visible Light and Microwave‐Mediated Rapid Trapping and Release of Singlet Oxygen Using a Coordination Polymer

Visible Light and Microwave‐Mediated Rapid Trapping and Release of Singlet Oxygen Using a Coordination Polymer

New Insights into Chitosan-Ag Nanocomposites Synthesis: Physicochemical Aspects of Formation, Structure-Bioactivity Relationship and Mechanism of Antioxidant Activity

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