Together we are stronger' In this work, the preparation of the quaternary nanocomposite TiO 2 /CdS/rGO/Pt is reported along with its application, for the first time, as a catalyst for the photocatalytic reduction of carbon dioxide (CO 2 ) to methane (CH 4 ). TiO 2 /CdS nanoparticles and Pt nanoparticle-decorated reduced graphene oxide sheets (rGO/Pt) were synthesized separately and characterized through X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), Raman spectroscopy, UV-vis spectroscopy and photoelectrochemical experiments. Hydrocarbon samples were collected and analysed using gas chromatography (GC). After 5 hours of illumination under visible light, 0.11 mmol of CH 4 was produced at an average production rate of 0.0867 mmol h À1 , which is higher than the production of CH 4 measured from the TiO 2 /CdS and the TiO 2 /CdS/Pt control samples. The photoelectrochemical experiments confirmed that the presence of rGO sheets in the nanocomposite enhanced the electrochemical and photocatalytic properties of the nanocomposite as a result of rapid electron transport and the inhibition of charge recombination.
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Preparation of quaternary nanocomposite TiO 2 /CdS/ rGO/PtNanocomposites were prepared by dispersing 1% by weight of rGO/Pt and TiO 2 /CdS into an isopropanol/water solution (2 : 1). The system was kept in an ultrasonic bath for 30 minutes to completely disperse the components in the solvent mixture. Aerwards, the suspension of the quaternary nanocomposite This journal is