Assessing the Adsorptive and Photodegradative Efficiencies of ZSM-11 Synthesized from Rice Husk Ash

Abstract

Rice husk was used to synthesize zeolite (ZSM-11). FTIR and X-ray diffraction methods were used to characterize the product. The synthesized zeolite was used to treat underground water from some communities in Cape Coast considering parameters such as total dissolved solids, total hardness, conductivity, nitrate, and phosphate. The percentage reduction in PO43− was 96.1% in Ebubonko and 92.5% in Apewosika. Similarly, the NO3− levels also decreased significantly in Kwaprow. The adsorption capability was also determined by using it to remove Pb2+ and Zn2+ from laboratory prepared solutions with varying masses. The percentage reduction recorded 90.57% and 86.61% for the 1.0 g whilst the 1.5 g showed 93.26% and 89.36%, respectively. It was also realized that the adsorption process followed a pseudo-first-order rather than the pseudo-second-order process with their R2 values of 0.9929 and 0.8503 for the pseudo-first-order and 0.9662 and 0.6912 for the second-order for Pb2+ and Zn2+, respectively. The adsorption capacity also favored the Freundlich isotherm with R2 values of 0.7578 and 0.642 rather than Langmuir isotherm with R2 values of 0.1742 and 0.3856 for Pb2+ and Zn2+, respectively. The photodegradation ability of the synthesized zeolite was analyzed using rhodamine blue (RhB) and methyl orange (MO). The process was realized to favor the pseudo-second-order with R2 values of 0.9986 and 0.0007 and a constant K2 of 0.035 and 0.021 for RhB and MO, respectively, whereas the pseudo-first-order showed an R2 value of 0.9376 and 0.9757 with K1 values of 0.03 and 0.02.

An efficient green protocol for the synthesis of 1,2,4,5-tetrasubstituted imidazoles in the presence of ZSM-11 zeolite as a reusable catalyst

“…With increased reactions time from 18 to 48 h, we observed that the intensity of the peak at 547 cm −1 was increased due to the percentage of aluminum insertion increases in the zeolite framework. 37 Hence, based on observed FT-IR and EDS results, it is concluded in this work that the synthesis of ZSM-11 zeolite type structure with MEL topology needs 3.17% of aluminum as well as 48 h for the completion of the reaction.…”