2023
DOI: 10.1039/d3nr01966g
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Assessment of biomass-derived carbon dots as highly sensitive and selective templates for the sensing of hazardous ions

Abstract: Access to safe drinking water and a hygienic living environment are the basic necessities that encourages healthy living. However, the presence of various pollutants especially heavy toxic metal ions in...

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Cited by 42 publications
(6 citation statements)
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“…An example of this is their ability to hybridize into sp, sp 2 , and sp 3 configurations based on the bonding relationships with neighboring atoms, and the narrow gap between the 2s and 2p electron shells, effectively facilitating the fabrication of a wide variety of carbon materials [117,118]. In particular, as electrode materials in sensors, carbonaceous nanomaterials demonstrate several unique properties for sensing and detection of a variety of analytes [119], such as the possibility of depositing electrocatalytic groups on the surface of these materials, the presence of edge-plane-like sites located at the ends and in defect areas of nanostructures, high surface area, efficient electronic properties, and unique 2D structures, such as in graphene and carbon nitride, etc. [120].…”
Section: Carbon Materials and Pd Nanocomposite-based Sensorsmentioning
confidence: 99%
“…An example of this is their ability to hybridize into sp, sp 2 , and sp 3 configurations based on the bonding relationships with neighboring atoms, and the narrow gap between the 2s and 2p electron shells, effectively facilitating the fabrication of a wide variety of carbon materials [117,118]. In particular, as electrode materials in sensors, carbonaceous nanomaterials demonstrate several unique properties for sensing and detection of a variety of analytes [119], such as the possibility of depositing electrocatalytic groups on the surface of these materials, the presence of edge-plane-like sites located at the ends and in defect areas of nanostructures, high surface area, efficient electronic properties, and unique 2D structures, such as in graphene and carbon nitride, etc. [120].…”
Section: Carbon Materials and Pd Nanocomposite-based Sensorsmentioning
confidence: 99%
“…Due to the strong affinity of heteroatomic groups on CDs surfaces toward metal ions, these CDs typically exhibit responsiveness toward a range of metal ions including Cu 2+ , Fe 2+ , Fe 3+ , Hg 2+ , and Pb 2+ . However, the application of heteroatom-doped CDs in Hg 2+ detection encounters certain challenges. The luminescence of heteroatoms doped CDs is susceptible to interference from other transition metal ions due to the presence of abundant functional groups such as −NH 2 , −COOH, −OH, and −SH, resulting in suboptimal performance in detection systems comprising multiple metal ions (e.g., coastal seawater) . Especially, coastal waters present a highly complex matrix characterized by diverse chemical species and interfering substances that can impede the accurate determination of Hg 2+ ions concentrations. , Therefore, the development of a novel class of CDs that is specifically designed for the detection of Hg 2+ in coastal seawater holds immense significance in safeguarding both marine ecosystems and human well-being.…”
Section: Introductionmentioning
confidence: 99%
“…19 Hence, CDs derived from biomass exhibit remarkable water solubility attributed to their inherent functionality. 20 They also exhibit strong uorescence without the need for additional surface treatment and display variable quantum yields, typically falling within the range of 2% to 6%, and in some instances, reaching up to 20%. 21 We have recently directed our research focus towards the electrochemical (EC) valorization of high-value molecules that remain within biomass.…”
Section: Introductionmentioning
confidence: 99%