Assessing the role
of volatile organic compounds (VOCs) in production
of ozone and secondary organic aerosol (SOA) is especially important
in light of ongoing policy goals. Here, we estimated the ozone formation
potential (OFP) and SOA formation potential (SOAP) of anthropogenic
and biogenic VOC emissions to evaluate (1) anthropogenic VOCs and
associated sectors that dominate OFP and SOAP and (2) the potential
impacts of enhanced biogenic VOCs from urban greening programs on
air quality in Los Angeles county. In the present-day scenario, ethylene
had the largest OFP followed by m & p-xylene, toluene, propylene, and formaldehyde. The top five contributors
to SOAP were toluene, mineral spirits, benzene, heptadecane, and hexadecane.
Mobile and solvent sources were the dominant VOC sources for both
OFP and SOAP. The potential increases in biogenic VOC emissions due
to future urban greening had significant effects on urban air quality
that offset the benefits of reducing anthropogenic VOC emissions.
This study demonstrates that urban greening programs in Los Angeles
county, and likely other cities as well, need to account for both
anthropogenic and biogenic VOC contributions to secondary pollution,
and greening cities should consider using vegetation types with low
VOC emissions to avoid further degradation to urban air quality.