In this chapter, we present an overview of the recent advances in analog-to-digital converter (ADC) neural networks. Biological neural networks consist of natural binarization reflected by the neurosynaptic processes. This natural analog-to-binary conversion ability of neurons can be modeled to emulate analog-to-digital conversion using a set of nonlinear circuit elements and existing artificial neural network models. Since one neuron during processing consumes on average only about half nanowatts of power, neurons can perform highly energy-efficient operations, including pattern recognition. Analog-to-digital conversion itself is an example of simple pattern recognition where input analog signal can be presented in one of the 2 N different patterns for N bits. The classical configuration of neural network-based ADC is Hopfield neural network ADC. Improved designs, such as modified Hopfield network ADC, T-model neural ADC, and multilevel neurons-based neural ADC, will be discussed. In addition, the latest architecture designs of neural ADC such as hybrid complementary metal-oxide semiconductor (CMOS)-memristor Hopfield ADC are covered at the end of this chapter.