“…The cross-linkable organic HTMs, 1-DTPA, 2-DTPA, 3-DTPA, and 4-DTPA, comprising DBF as the core and TPA as the end group with disubstituted vinyl moieties as cross-linking functional groups, were synthesized. DBF was chosen as the core owing to its low cost, high thermal stability, and structural tunability, allowing the introduction of various substituents. − In addition, substitution in the DBF core significantly improves hole transport characteristics. A well-known hole transport disubstituted vinyl TPA unit was introduced at the 1, 2, 3, and 4 positions of the DBF core.…”