Sulfate (SO 4 2−) has been recognized as a key and major component of fine particulate matter (PM) with an aerodynamic diameter of 2.5 µm or smaller (PM 2.5) in the atmosphere, especially during severe haze events (Cheng et al., 2016; Huang et al., 2014; Shah et al., 2018). SO 4 2− directly impacts the solar radiative balance and the physicochemical properties of aerosols (Tsigaridis & Kanakidou, 2018). Ground-based observations from 2005 to 2014 have revealed that the averaged proportions of sulfate in the atmospheric PM 2.5 mass are 15% ± 6% and 20% ± 5% in northern and southern China, respectively (Zhang et al., 2017). The SO 4 2− concentration has been intensively studied via modeling by mainly focusing on its formation through atmospheric SO 2 oxidation (secondary formation) to determine a sufficient chemical production mechanism (R. Zhang et al., 2015). However, a knowledge gap (also referred to as missing sulfate) remains in regards to our understanding of the sources and formation pathways of high SO 4 2− concentrations, especially during Chinese winter haze periods (