2011
DOI: 10.1063/1.3622304
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Atomistic mechanisms of moisture-induced fracture at copper-silica interfaces

Abstract: Articles you may be interested inMode I fracture toughness behavior of hydro-thermally aged carbon fibre reinforced DGEBA-HHPA-PES systems AIP Conf.

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Cited by 9 publications
(6 citation statements)
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“…4,5 On a related note, we point out that molecular functionalization and the accompanying moisture have been shown to impact a plethora of properties (including chemical, mechanical, dielectric, and electronic properties). [6][7][8][9] In the present work, using parameter-free first principles density functional theory (DFT) computations, we provide further evidence for the presence of water when -OH groups are incorporated in a polyolefin. Furthermore, we also show that the dielectric constant of polyolefins increases successively as -OH groups, and, subsequently, water molecules are added to the polyolefin system.…”
mentioning
confidence: 76%
“…4,5 On a related note, we point out that molecular functionalization and the accompanying moisture have been shown to impact a plethora of properties (including chemical, mechanical, dielectric, and electronic properties). [6][7][8][9] In the present work, using parameter-free first principles density functional theory (DFT) computations, we provide further evidence for the presence of water when -OH groups are incorporated in a polyolefin. Furthermore, we also show that the dielectric constant of polyolefins increases successively as -OH groups, and, subsequently, water molecules are added to the polyolefin system.…”
mentioning
confidence: 76%
“…At the nanometer length scales, the interfacial area per unit volume is significantly increased, and thus the bulk mechanical properties of the multilayers are dominated by interfaces [5]. We showed in our previous work that different interface chemistries might lead to contrasting ideal shear strength behaviors at the Al-TiN interface [6], thereby adding to the considerably vast literature on this topic [7][8][9][10].…”
Section: Introductionmentioning
confidence: 84%
“…21 Scission of specific bonds within interfacial MNLs eliminates crack-path uncertainties that otherwise confound fracture energy partitioning into work of adhesion and plasticity during interfacial delamination and stress corrosion. [22][23][24] MNL-induced toughening also correlates with enhanced thermal transport, 18 contrary to the expectation of curtailed phonon transport across organic layers.…”
mentioning
confidence: 79%