1972
DOI: 10.1177/001391657200400101
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Cited by 33 publications
(2 citation statements)
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“…Ionomers of ethylene-propylene-diene copolymer (EPDM) or butyl rubber can be prepared by sulfonation in solution with acetyl sulfate and behave as thermoplastic elastomers in the presence of an ionic plasticizer. [1][2][3][4][5] Xie and Xu 6 pointed out that it is not necessary to use zinc stearate during the processing of alkylamine neutralized ionomers of sulfonated butyl rubber. However, Fitzgerald and Weiss 7 pointed out that rubber with a higher unsaturation degree cannot be sulfonated in solution at concentrations over 3% so as to avoid gelation.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…Ionomers of ethylene-propylene-diene copolymer (EPDM) or butyl rubber can be prepared by sulfonation in solution with acetyl sulfate and behave as thermoplastic elastomers in the presence of an ionic plasticizer. [1][2][3][4][5] Xie and Xu 6 pointed out that it is not necessary to use zinc stearate during the processing of alkylamine neutralized ionomers of sulfonated butyl rubber. However, Fitzgerald and Weiss 7 pointed out that rubber with a higher unsaturation degree cannot be sulfonated in solution at concentrations over 3% so as to avoid gelation.…”
Section: Introductionmentioning
confidence: 99%
“…SBS was first epoxidized by performic acid in the presence of a phase-transfer catalyst; this was followed by a ring-opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring-opening reaction of the epoxidized SBS with an aqueous solution of KHSO 4 were studied. During the ring-opening reaction, both phase-transfer catalyst and ring-opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups.…”
mentioning
confidence: 99%