A method of interconnecting micropad electrodes was developed by using the electroless deposition of NiB for application to the flip-chip bonding technology. The phenomenon of "bridge" formation by the so-called "extraneous deposition" was utilized as a technique to perform selective deposition of NiB on noncatalytic surfaces. The process of extraneous electroless deposition was controlled by optimizing deposition conditions so that the deposit grew anisotropically along the surface between the facing pads. Practical feasibility of this technique was demonstrated by forming an interconnection between pads separated by 5 m and measuring 5 m in both height and width. This method was applied successfully to interconnecting the pads forming an array with a pitch of 20 m.To meet the strong demand for high performance electronic packaging, interconnection technology involving chip-to-chip and chip-to-substrate bonds is a key element controlling the performance of electronic instruments. 1-3 In this packaging technology, the reliability of interconnection of high-density pad electrodes in three dimensions is very important. Currently, several methods, including wire bonding, tape automated bonding ͑TAB͒, and flip-chip bonding, are being used widely. Especially, the method of flip-chip bonding with small metal bumps is used more widely than other methods for fine-pitch bonding, as the former technology is more compatible with a higher packaging density with a shorter electrical path because of the use of a fine-bump array with a fine pitch. 4 Many researchers have investigated this method. 5,6 However, fine-pitch arrays of bumps of the order of micrometers in height and width are not easy to fabricate. Moreover, insufficient accuracy in alignment in the chip-to-substrate bonding is becoming a serious problem in dealing with finer bumps. 1 Furthermore, chip damages caused by pressure and heat treatment during bump bonding are also becoming a problem. 1,2 For solving these problems, several researchers have investigated the chip-to-substrate connection using the "surface activated bonding" method at room temperature 7 and the electroless deposition method. 8,9 In this article, we propose a method of pad interconnection using electroless metal deposition as a technique with a potential of application to flip-chip bonding technology. In this method, a metal is deposited electrolessly on organic resin to connect pads without using a seed layer and a resist pattern delineated by photolithography. No heat treatment nor pressure application is required, and the temperature during this fabrication process is as low as 60°C. This method is believed to be useful as a process for forming interconnections in technologies including three-dimensional system integration.Generally, it is known that electroless deposition, especially electroless NiB deposition, can occur not only on catalytic surfaces but also on noncatalytic surfaces near a catalytic area. 10-18 This phenomenon is called "extraneous deposition," and it is known to cause ...