AuNP–Polymeric Ionic Liquid Composite Multicatalytic Nanoreactors for One-Pot Cascade Reactions

Abstract

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Poly(ionic liquid) composites

“…2). 91 The structural analysis revealed that appropriately controlling the self-assembly and self-organization of the constitutive building blocks during their synthesis can optimize the microenvironments for each reaction, determining the diffusion of the intermediates from the shell to the core and out from the core to the reaction media.…”

Synthesis of multifunctional polymer containing Ni‐Pd NPs via thiol‐ene reaction for one‐pot cascade reactions

“…To the best of our knowledge, there are only two reports about the reduction of α‐cyano‐α,β‐unsaturated esters …”

“…In other reports, Luis et.al reported two‐step Knoevenagel reaction‐reduction over a bifunctional catalyst containing Au nanoparticles . They could reduce the alkane, ester and nitro groups to alkane, alcohol and amine groups at 24 hr using 20 mmol NaBH 4 .…”

Ru@PsIL‐Catalyzed Synthesis of N‐Formamides and Benzimidazole by using Carbon Dioxide and Dimethylamine Borane

“…The synthesis of the Ru@PsIL catalyst was performed by modifying the reported procedure (Figure S2 in the Supporting Information) . Typically, the Ru@PsIL was synthesized by the immobilization of Merrifield peptide resin with 1,2‐dimethyl‐1 H ‐imidazole to give PsIL (Scheme S2 in the Supporting Information).…”

“…The presence of functional moieties with ionic nature in the polymer backbone enhances the dispersion and stabilization of NPs. Also, the immobilized ILs as supports for catalysts, not only benefit from the excellent physicochemical properties of ILs but also help in increasing the recyclability of catalysts and ease catalyst–product separation . The immobilization of ILs on polymers lets them act as a solid support and provide a similar electronic environment as ILs for the stabilization of NPs…”