Author Correction: Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons

Zhou, Yansong; Che, Fanglin; Liu, Min; Zou, Chengqin; Liang, Zhiqin; Luna, Phil De; Yuan, Haifeng; Li, Jun; Wang, Zhi–Qiang; Xie, Haipeng; Li, Hongmei; Chen, Peining; Bladt, Eva; Quintero-Bermúdez, Rafael; Sham, Tsun‐Kong; Bals, Sara; Hofkens, Johan; Sinton, David; Chen, Gang; Sargent, Edward H.

doi:10.1038/s41557-019-0381-z

Cited by 11 publications

(9 citation statements)

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“…However, the present issues, such as low selectivity toward a specific product and low FE due to competition with HER and sluggish kinetics, still need to be addressed [76,81,84,85,90,91]. In recent years, various interface-related strategies have been devised to enhance its catalytic performance, such as intermetallic compounds [92], heteroatomic doping [68,93], single Cu atom catalysts [94], core-shell structures [86], and heterostructure [95][96][97]. Among them, alloying is a general and widespread method to improve catalytic performance [98][99][100].…”

Section: Metal-metal Interfacementioning

confidence: 99%

“…4f). The theoretical model that a ceria nanoparticle is immobilized on Cu-slab based on Graciani et al was built to explore the interface effect of Cu/CeO 2−x [93]. At the microlevel, the enhancement results from bidentate adsorption and stability of CHO* and H 2 CO* on Cu and oxygen vacancies in CeO 2−x , which is conducive to thermodynamically favored pathway toward C 1 by breaking the CHO*/ CO* scaling relationship [145][146][147][148][149][150].…”

Section: Metal-metal Oxide Interfacementioning

confidence: 99%

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Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Abbas

Wang

et al. 2021

Nano-Micro Lett.

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Electrocatalytic CO2 reduction reaction (CO2RR) can store and transform the intermittent renewable energy in the form of chemical energy for industrial production of chemicals and fuels, which can dramatically reduce CO2 emission and contribute to carbon-neutral cycle. Efficient electrocatalytic reduction of chemically inert CO2 is challenging from thermodynamic and kinetic points of view. Therefore, low-cost, highly efficient, and readily available electrocatalysts have been the focus for promoting the conversion of CO2. Very recently, interface engineering has been considered as a highly effective strategy to modulate the electrocatalytic performance through electronic and/or structural modulation, regulations of electron/proton/mass/intermediates, and the control of local reactant concentration, thereby achieving desirable reaction pathway, inhibiting competing hydrogen generation, breaking binding-energy scaling relations of intermediates, and promoting CO2 mass transfer. In this review, we aim to provide a comprehensive overview of current developments in interface engineering for CO2RR from both a theoretical and experimental standpoint, involving interfaces between metal and metal, metal and metal oxide, metal and nonmetal, metal oxide and metal oxide, organic molecules and inorganic materials, electrode and electrolyte, molecular catalysts and electrode, etc. Finally, the opportunities and challenges of interface engineering for CO2RR are proposed.

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Section: Metal-metal Interfacementioning

confidence: 99%

Section: Metal-metal Oxide Interfacementioning

confidence: 99%

Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Abbas

Wang

et al. 2021

Nano-Micro Lett.

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“…, ethanol and ethylene). 7,8 However, the conventional CO 2 RR systems usually exhibit undesirable energy conversion efficiency due to the complex multi-electron reaction on the cathode surface and endothermic reaction with considerable barrier. 9 In contrast, direct electrochemical CO 2 RR by means of novel energy storage devices is a promising strategy to enhance CO 2 capture and improve energy conversion efficiency.…”

Section: Introductionmentioning

confidence: 99%

Recent progress of transition metal-based catalysts as cathodes in O₂/H₂O-involved and pure Li–CO₂batteries

Chen

Liu

et al. 2023

Energy Environ. Sci.

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“…However, the two tricky issues are hard to solve simultaneously. In addition, it has been proved that the morphology, [10, 11] oxidation state [12–14] and lattice planes [15, 16] of the Cu catalyst have a significant influence on the selectivity of CO 2 RR. Therefore, achieving high selectivity for CH 4 in a Cu‐based electrocatalyst system remains a great challenge.…”

Section: Introductionmentioning

confidence: 99%

Constructing Cu−C Bonds in a Graphdiyne‐Regulated Cu Single‐Atom Electrocatalyst for CO₂ Reduction to CH₄

et al. 2022

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Regulating intermediates through elaborate catalyst design to control the reaction direction is crucial for promoting the selectivity of electrocatalytic CO 2 -to-CH 4 . MÀ C (M = metal) bonds are particularly important for tuning the multi-electron reaction; however, its construction in nanomaterials is challenging. Here, via rational design of in situ anchoring of Cu SAs (single atoms) on the unique platform graphdiyne, we firstly realize the construction of a chemical bond CuÀ C (GDY). In situ Raman spectroelectrochemistry and DFT calculations confirm that due to the fabrication of the CuÀ C bond, during CO 2 reduction, the formation of *OCHO intermediates is dominant rather than *COOH on Cu atoms, facilitating the formation of CH 4 . Therefore, we find that constructing the CuÀ C bond in Cu SAs/GDY can supply an efficient charge transfer channel, but most importantly control the reaction intermediates and guide a more facile reaction pathway to CH 4 , thereby significantly boosting its catalytic performance. This work provides new insights on enhancing the selectivity for CO 2 RR at the atomic level.

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Author Correction: Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons

Abstract: In the version of this Article originally published, in Table 1, the H 2 Faradaic efficiency for Cu(C) incorrectly read 66.4%; it should have been 36 ± 2%. This has now been corrected.

Cited by 11 publications

References 0 publications

Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Recent progress of transition metal-based catalysts as cathodes in O₂/H₂O-involved and pure Li–CO₂batteries

Constructing Cu−C Bonds in a Graphdiyne‐Regulated Cu Single‐Atom Electrocatalyst for CO₂ Reduction to CH₄

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Author Correction: Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons

Abstract: In the version of this Article originally published, in Table 1, the H 2 Faradaic efficiency for Cu(C) incorrectly read 66.4%; it should have been 36 ± 2%. This has now been corrected.

Cited by 11 publications

References 0 publications

Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction

Recent progress of transition metal-based catalysts as cathodes in O2/H2O-involved and pure Li–CO2batteries

Constructing Cu−C Bonds in a Graphdiyne‐Regulated Cu Single‐Atom Electrocatalyst for CO2 Reduction to CH4

Contact Info

Product

Resources

About

Recent progress of transition metal-based catalysts as cathodes in O₂/H₂O-involved and pure Li–CO₂batteries

Constructing Cu−C Bonds in a Graphdiyne‐Regulated Cu Single‐Atom Electrocatalyst for CO₂ Reduction to CH₄