The chemical abundances of spiral galaxies, as probed by H II regions across their disks, are key to understanding the evolution of galaxies over a wide range of environments. We present LBT/MODS spectra of 52 H II regions in NGC3184 as part of the CHemical Abundances Of Spirals (CHAOS) project. We explore the direct-method gas-phase abundance trends for the first four CHAOS galaxies, using temperature measurements from one or more auroral line detections in 190 individual H II regions. We find the dispersion in T e − T e relationships is dependent on ionization, as characterized by F λ5007 /F λ3727 , and so recommend ionization-based temperature priorities for abundance calculations. We confirm our previous results that [N II] and [S III] provide the most robust measures of electron temperature in low-ionization zones, while [O III] provides reliable electron temperatures in highionization nebula. We measure relative and absolute abundances for O, N, S, Ar, and Ne. The four CHAOS galaxies marginally conform with a universal O/H gradient, as found by empirical IFU studies when plotted relative to effective radius. However, after adjusting for vertical offsets, we find a tight universal N/O gradient of α N/O = −0.33 dex/R e with σ tot. = 0.08 for R g /R e < 2.0, where N is dominated by secondary production. Despite this tight universal N/O gradient, the scatter in the N/O-O/H relationship is significant. Interestingly, the scatter is similar when N/O is plotted relative to O/H or S/H. The observable ionic states of S probe lower ionization and excitation energies than O, which might be more appropriate for characterizing abundances in metal-rich H II regions.
Spectral ReductionsFor a detailed description of the data reduction procedures we refer the reader to (B15). Here, we only note the primary points of our data processing. Spectra were reduced and analyzed using the beta-version of the MODS reduction pipeline 1 which runs within the XIDL 2 reduction package. Given that the bright disks of CHAOS galaxies can complicate local sky subtraction, 1