B(C6F5)3-catalyzed oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources

Wang, Bei; Zhang, Guomin; Zhang, Hua; Wang, Jiyu

doi:10.1039/d2ra05739e

RSC Adv.

2022

DOI: 10.1039/d2ra05739e

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B(C₆F₅)₃-catalyzed oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources

Bei Wang

Guomin Zhang

Hua Zhang

et al.

Abstract: B(C6F5)3-catalyzed synthesis of α-ketoesters via the oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources..

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2023

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A Palladium-Catalyzed Carbonylative Acetylation of N-Phenylpyridin-2-amine Using DMF and CO as the Acetyl Source

Wang

et al. 2023

J. Org. Chem.

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This study reports a carbonylative acetylation for the synthesis of N-phenyl-N-(pyridin-2-yl)acetamides using N,N-dimethylformamide (DMF) as a methyl source and CO as a carbonyl source. Interestingly, dimethyl sulfoxide (DMSO) can be also used as a methyl source when using only DMSO as the solvent. Mechanistic studies using DMSO-d 6 revealed that the methyl group was derived from the methyl group of DMF instead of DMSO when using DMF and DMSO as a mixed solvent. These results indicated that DMF was a preferential methyl source.

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A Palladium-Catalyzed Carbonylative Acetylation of N-Phenylpyridin-2-amine Using DMF and CO as the Acetyl Source

Wang

et al. 2023

J. Org. Chem.

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show abstract

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B(C₆F₅)₃-catalyzed oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources

Abstract: B(C6F5)3-catalyzed synthesis of α-ketoesters via the oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources..

Cited by 1 publication

References 65 publications

A Palladium-Catalyzed Carbonylative Acetylation of N-Phenylpyridin-2-amine Using DMF and CO as the Acetyl Source

A Palladium-Catalyzed Carbonylative Acetylation of N-Phenylpyridin-2-amine Using DMF and CO as the Acetyl Source

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