2017
DOI: 10.1002/ange.201610768
|View full text |Cite
|
Sign up to set email alerts
|

BAB‐random‐C Monomer Sequence via Radical Terpolymerization of Limonene (A), Maleimide (B), and Methacrylate (C): Terpene Polymers with Randomly Distributed Periodic Sequences

Abstract: An aturally abundant terpene,l imonene (A), was radically polymerized with am aleimide derivative (B) and methacrylate (C) in af luorinated alcohol to give terpolymers with unprecedented BAB-random-C sequences in whicht he BABm onomer sequence was randomly copolymerized with aC unit. In eachb inary system, limonene was hardly copolymerized with methacrylate while it was efficiently copolymerized with maleimide to result in a1 :2-alternating BABp eriodic sequence,i np art due to the penultimate effects and hydr… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1
1

Citation Types

0
7
0

Year Published

2017
2017
2024
2024

Publication Types

Select...
9

Relationship

0
9

Authors

Journals

citations
Cited by 15 publications
(7 citation statements)
references
References 47 publications
0
7
0
Order By: Relevance
“…57,62,64−66 Meanwhile, PMI is also regarded as a nonhomopolymerizable monomer (propagation rate constant is very low). 56,57,62,65,67,68 The final polymers therefore present alternating nature of PMI and Ane. Although the copolymerization might bring complicated propagation kinetics (reinitiation of polymer chain with two possible chain ends derived from Ane and PMI, diverse chain transfer, and termination), only the consumption of RAFT agents, Dia1 and Dia2, was monitored, which mostly involves the photoactivation of RAFT agents during initiation step and the activation caused by chain transfer.…”
Section: Macromoleculesmentioning
confidence: 99%
“…57,62,64−66 Meanwhile, PMI is also regarded as a nonhomopolymerizable monomer (propagation rate constant is very low). 56,57,62,65,67,68 The final polymers therefore present alternating nature of PMI and Ane. Although the copolymerization might bring complicated propagation kinetics (reinitiation of polymer chain with two possible chain ends derived from Ane and PMI, diverse chain transfer, and termination), only the consumption of RAFT agents, Dia1 and Dia2, was monitored, which mostly involves the photoactivation of RAFT agents during initiation step and the activation caused by chain transfer.…”
Section: Macromoleculesmentioning
confidence: 99%
“…Sequence-controlled polymers, whose monomer units of different chemical nature are arranged in an ordered fashion, are of great interest to polymer scientists. Biopolymers such as DNA, RNA, and proteins with ordered sequences of building blocks are well-known sequence-controlled natural polymers, with their biological functions highly dependent on the structures, in particular, the strict sequence of subunits. To realize biomimic synthesis, while the current polymerization techniques for the precise control of molecular weights and their distributions are well-developed, the construction of non-natural sequence-defined polymers remains a great challenge for polymer chemists. The current method for sequence-controlled synthetic polymers is mainly based on solid-phase synthesis.…”
Section: Introductionmentioning
confidence: 99%
“…Additionally, by integrating terpenes in a polymer network, elasticity of the resulting material increases due to the isoprene like structure of these compounds. The studies performed on different types of terpenes has shown that due to high reactivity and regioselectivity of terpenes, polymerization of this compounds generally results with polymers with different chemical structures due to the tendency of terpene molecules to react with its monomers, inself [21]. Among previous studies, emulsion polymerization is widely preferred as a polymerization method in free radical polymerization of linear terpenes [22][23][24][25].…”
Section: Resultsmentioning
confidence: 99%