Energy fuels retrieved from biomass utilization are considered to be an economically and environmentally friendly source. In this day and age, bioenergy provides an alternative option to replace traditional fossil-based energy to accomplish energy demand with fewer greenhouse gas emissions into the environment. A huge amount of food waste is produced every year due to mass ethnographic activities. Their potential has been underused and this has led to waste ending up in the garbage. Bioenergy production by anaerobic digestion of cheap substrate provides an effectual approach to cope with this issue. The hydrolysis stage during anaerobic digestion is enhanced by various pretreatment methods, where the disintegration of the waste substrate leads to the enhancement of soluble organics and eases the production of bioenergy. The present review focuses on state-of-the-art knowledge about food waste, its utilization, and its valorization by the action of pretreatment, thereby enhancing anaerobic digestion. Additionally, this review further focuses on the major challenges during the pretreatment method and future recommendations.