This paper reviews. the most recent experimental results concerning the characterization of hot-electron effects and light emission^ in GaAs MESFETS, AIGaAsIGaAs and AIGaAs/lnGaAs high electron mobility transistors (HEMTS), and AIGaAsIGaAs heterojunction bipolar transistors (HBTs). In MESFETS and HEMTS, light emission has been correlated with impact-ionization-induced gate current, providing insights into possible emission mechanisms. In HBTs, impact ionization can be evaluated by measuring the changes In the base current as a function of base-collector voltage. The measured multiplication factor correlates well with the results of a Monte Carlo simulation of the device, which also provides general microscopic details ofthe pre-avalanche regime.