Considering that, in the context of the ecological restoration of a large number of exposed rock slopes, it is difficult for existing artificial soil to meet the requirements of mechanical properties and ecological construction at the same time, this paper investigates the stabilization benefits of polyvinyl acetate and attapulgite-treated clayey soil through a series of laboratory experiments. To study the effectiveness of polyvinyl acetate (PVA) and attapulgite as soil stabilizer, a triaxial strength test, an evaporation test and a vegetation growth test were carried out on improved soil with different amounts of PVA content (0, 1%, 2%, 3%, and 4%) and attapulgite replacement (0, 2%, 4%, 6%, and 8%). The results show that the single and composite materials of polyvinyl acetate and attapulgite can increase the peak deviator stress of the sample. The addition of polyvinyl acetate can improve the soil strength by increasing the cohesion of the sample; the addition of attapulgite improves the soil strength mainly by increasing the internal friction angle of the sample. The strength of the composite is greatly improved by increasing the cohesion and internal friction angle of the sample at the same time. The effect of adding materials increased significantly with increasing curing age. Moreover, polyvinyl acetate and attapulgite improve the soil water retention of the soil by improving the water-holding capacity, so that the soil can still ensure the good growth of vegetation under long-term drought conditions. The scanning electron microscopy (SEM) images indicated that the PVA and attapulgite of soil affect the strength characteristics of soil specimens by the reaction of PVA and water, which changes the structure of the soil and, by the interweaving of attapulgite soil particles, acts as the skeleton of the aggregate. Overall, PVA and attapulgite can effectively increase clayey soil stability by improving the cohesive force and internal friction angle of clayey soil.