Abstract. Mixing ratios of volatile organic compounds (VOCs) were recorded
in two field campaigns in central Beijing as part of the Air Pollution and
Human Health in a Chinese Megacity (APHH) project. These data were used to
calculate, for the first time in Beijing, the surface–atmosphere fluxes of
VOCs using eddy covariance, giving a top-down estimation of VOC emissions
from a central area of the city. The results were then used to evaluate the
accuracy of the Multi-resolution Emission Inventory for China (MEIC). The
APHH winter and summer campaigns took place in November and December 2016
and May and June 2017, respectively. The largest VOC fluxes observed were of
small oxygenated compounds such as methanol, ethanol + formic acid and
acetaldehyde, with average emission rates of 8.31 ± 8.5, 3.97 ± 3.9 and 1.83 ± 2.0 nmol m−2 s−1, respectively, in the summer.
A large flux of isoprene was observed in the summer, with an average emission
rate of 5.31 ± 7.7 nmol m−2 s−1. While oxygenated VOCs made
up 60 % of the molar VOC flux measured, when fluxes were scaled by ozone
formation potential and peroxyacyl nitrate (PAN) formation potential the
high reactivity of isoprene and monoterpenes meant that these species
represented 30 % and 28 % of the flux contribution to ozone and PAN
formation potential, respectively. Comparison of measured fluxes with the
emission inventory showed that the inventory failed to capture the magnitude
of VOC emissions at the local scale.