Benzyldiethylammonium chloride

Abstract

Key indicatorsSingle-crystal X-ray study T = 150 K Mean (C-C) = 0.003 Å R factor = 0.035 wR factor = 0.070 Data-to-parameter ratio = 19.0For details of how these key indicators were automatically derived from the article, see

Crystal structure of 1,1,4,7,7-pentamethyldiethylenetriammonium chloride, [C9H26N3]Cl3

“…This detail indicates that C−H···Cl bonds are weaker than N−H···Cl hydrogen bonds. Similar structural elements occur in the crystal structures of 1-butyl-3-cyclododecyloxymethylimidazolium chloride monohydrate [4] and benzyldiethylammonium chloride [5]. …”

The Lithium Salts of Bis(azolyl)borates as Strontium‐ and Chlorine‐free Red Pyrotechnic Colorants

“…In general, the B–H and B–N distances as well as the N–B–N bond angles of compounds 1 – 4 are in the range of reported values for potassium dihydrobis(pyrazol‐1‐yl)borate (B–N 1.561 Å; N–B–N 110.6°), barium dihydrobis(1,2,4‐triazol‐1‐yl)borate trihydrate[10c] (B–N 1.543–1.559 Å) and potassium dihydrobis(tetrazol‐1‐yl)borate[10e] (B–H 1.09–1.10 Å, B–N 1.553–1.561 Å; N–B–N 109.1°). The B–H bond lengths decrease and the B–N bonds are elongated when replacing 1 H ‐pyrazole as the substituent by 1 H ‐1,2,4‐triazole or 1 H ‐tetrazole, respectively.…”