A rapid chemical method has been developed for the synthesis of the CdTe nanoribbons with cubic crystalline phase. The method is based on the template-engaged synthesis in which the Te nanowires were used as template reagents. On the basis of a series of experiments and characterizations, the electrochemical property of CdTe nanoribbons was determined by the voltammetric technique. Furthermore, electrochemiluminescence property of CdTe nanoribbons was investigated. The results show that CdTe nanoribbons are helpful to obtain stable electrochemiluminescence emission for 1200 seconds.