Binuclear iron(III) compounds with bidentate bases

Magnetic response of photonic crystals based on nucleating agents of binuclear complexes

“…The calculated separation (Dn) between the two peaks was 137 cm À1 , which is close to the bridging bidentate carboxylate group, thus confirming that Fe 3+ and Fe 2+ ligated with acetate in the precursor to form a mixed-valence binuclear iron complex. [59][60][61][62][63][64][65] Based on these experimental results, a nucleation mechanism for the synthesis of nano Fe 3 O 4 MRPCs by the solvothermal reduction method was proposed, in which mixed-valence binuclear iron served as the nucleating agent (Fig. 5).…”

“…The calculated separation (Δ ν ) between the two peaks was 137 cm −1 , which is close to the bridging bidentate carboxylate group, thus confirming that Fe 3+ and Fe 2+ ligated with acetate in the precursor to form a mixed-valence binuclear iron complex. 59–65…”