The compound, Fe2CIa(OH)2(MeCO2)2 " 2MeCO2It " H20, combines with lithium and silver acetates to form Fe2CI(OH)2(MeCO2)3 " 2MeCO2t-I and Fe2(OH)2(MeCO2)4 • H20, respectively. Iron(Ill) chloride in tetrahydrofuran reacts with silver acetate to give a precipitate consisting of a mixture of Fe(MeCO2)3 and AgCI which, when extracted with boiling acetic acid, yields " To whom all correspondence should be addressed. Fe202(MeCO2)2 3MeCO2H. With DMSO on theother hand an adduct Fe(MeCO2)3 • DMSO is formed which loses DMSO in vacuo to give ferric acetate, Fe(MeCO2)3. l.r. spectra, molar conductance, thermal decomposition, molecular weight and magnetic susceptibility measurements are reportcd.

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