Bio-based ether solvent and ionic liquid electrolyte for sustainable sodium–air batteries

Stigliano, Pierre L.; Ortiz-Vitoriano, Nagore; Medinilla, Lidia; Bara, Jason E.; López del Amo, Juan Miguel; Lezama, Luis; Forsyth, Maria; Mecerreyes, David; Pozo-Gonzalo, Cristina

doi:10.1039/d3fd00096f

Faraday Discuss.

2024

DOI: 10.1039/d3fd00096f

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Bio-based ether solvent and ionic liquid electrolyte for sustainable sodium–air batteries

Pierre L. Stigliano,

Nagore Ortiz-Vitoriano,

Lidia Medinilla

et al.

Abstract: Sodium-air batteries (SABs) are receiving considerable attention for the development of next generation battery alternatives due to their high theoretical energy density (up to 1105 Wh kg-1). However, most of...

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2024

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Cited by 2 publications

References 59 publications

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Harnessing the Potential of (Quasi) Solid‐State Na‐Air/O₂ Batteries: Strategies and Future Directions for Next‐Generation Energy Storage Solutions

Yahia,

de Larramendi,

Ortiz‐Vitoriano

2024

Advanced Energy Materials

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This perspective points out the potential of solid‐state Na‐air/O2 batteries for powering next‐generation storage devices, highlighting their high energy density, efficiency, and cost‐effectiveness. The challenges faced by Na‐air/O2 batteries, including liquid electrolyte instability, O2/O2− crossover, Na anode passivation, and dendritic growth are addressed. Strategies such as exploring solid‐state electrolytes (SSE), mitigating O2/O2− crossover, protecting the Na anode, and enhancing the solid electrolyte interphase (SEI) are discussed as potential solutions. Future challenges in advancing the technology are reviewed, emphasizing the need for addressing and understanding the fundamental mechanisms of (quasi)solid‐state Na‐air/O2 batteries (i.e., discharge product chemistry, dendritic growth, O2 crossover, the electrolyte properties, the stabilization of battery chemistry and Na+ transport). A roadmap outlining future directions is presented to overcome these challenges, with the goal of fully harnessing the potential of Na‐air/O2 batteries as a viable option for renewable energy and industrial‐scale commercialization.

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Harnessing the Potential of (Quasi) Solid‐State Na‐Air/O₂ Batteries: Strategies and Future Directions for Next‐Generation Energy Storage Solutions

Yahia,

de Larramendi,

Ortiz‐Vitoriano

2024

Advanced Energy Materials

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Solvate Ionic Liquids based on branched glymes enabling high performance lithium metal batteries

Lingua,

Depraetère,

Wang

et al. 2024

Journal of Power Sources

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Bio-based ether solvent and ionic liquid electrolyte for sustainable sodium–air batteries

Abstract: Sodium-air batteries (SABs) are receiving considerable attention for the development of next generation battery alternatives due to their high theoretical energy density (up to 1105 Wh kg-1). However, most of...

Cited by 2 publications

References 59 publications

Harnessing the Potential of (Quasi) Solid‐State Na‐Air/O₂ Batteries: Strategies and Future Directions for Next‐Generation Energy Storage Solutions

Harnessing the Potential of (Quasi) Solid‐State Na‐Air/O₂ Batteries: Strategies and Future Directions for Next‐Generation Energy Storage Solutions

Solvate Ionic Liquids based on branched glymes enabling high performance lithium metal batteries

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