Bio-resourced furan resin as a sustainable alternative to petroleum-based phenolic resin for making GFR polymer composites

Ipakchi, Hossein; Shegeft, Atefeh; Rezadoust, Amir Masoud; Zohuriaan‐Mehr, M. J.; Kabiri, Kourosh; Sajjadi, Samahe

doi:10.1007/s13726-020-00793-w

Cited by 18 publications

(7 citation statements)

References 44 publications

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“…The reinforcement of FAlc resins with various fillers allows obtaining high-performance materials with desired properties. The mechanical properties, chemical and thermal stabilities, thermal conductivity and flame retardancy can be tuned by the addition of an organically modified woven glass fiber and talc filler 368 or organically modified glass microspheres. 369 Fully bio-based composites can be prepared by furan resin copolymerization with tung oil and bacterial cellulose fibers 370 or by compression forming with bamboo culms, resulting in construction materials with a remarkable compressive strength and excellent recovery characteristics.…”

Section: Branched Typementioning

confidence: 99%

Recent advances in the development of green furan ring-containing polymeric materials based on renewable plant biomass

Karlinskii

Ananikov

2023

Chem. Soc. Rev.

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Section: Branched Typementioning

confidence: 99%

Recent advances in the development of green furan ring-containing polymeric materials based on renewable plant biomass

Karlinskii

Ananikov

2023

Chem. Soc. Rev.

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“…Phenolic resins from biomasses have been indeed developed and studied extensively in recent decades, but the search for biobased alternative to standard phenolic in the specific sector of high charring matrices is still ongoing (Loganathan et al, 2021), even though it is predictable that the properties of resin synthesized from bioresources are lower than the raw material derived from oil (Ipakchi et al, 2020;Ma et al, 2020;Guo et al, 2021;Gruber et al, 2021). One example of nanofiller reinforced phenolic composites for ablative purposes comes from the paper of Ma et al, where the authors found that the addition of graphene oxide or graphitic carbon nitride (Figure 8C) (Ma et al, 2019) increased the char yield graphitization level during ablation, helping heat dissipation and thereby increasing the ablation resistance.…”

Section: Phenolicsmentioning

confidence: 99%

High Temperature Composites From Renewable Resources: A Perspective on Current Technological Challenges for the Manufacturing of Non-Oil Based High Char Yield Matrices and Carbon Fibers

et al. 2022

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During last decades a plethora of high temperature materials have been developed to work as a Thermal Protection System (TPS). Carbon based materials such as graphite, which possesses low density, high heat capacity and high energy of vaporization, have been used as TPS material. However, graphite has relatively poor mechanical properties, but exhibits low resistance to the thermal shocks. Accordingly, to bypass the limitation of graphite, carbon fibers are typically introduced in a carbon matrix to produce Carbon/Carbon Composites (CCCs). Among the different families of TPS solutions, Polymeric Ablative Materials (PAMs), produced combining high char yield matrices - mainly phenolic resins - and Carbon Fibers (CFs) are used to manufacture Carbon/Phenolic Composites (CPCs) i.e. the most important class of fiber reinforced PAM. Carbon fibers are traditionally produced from Polyacrylonitrile (PAN), Rayon and Pitch. Some limited researches also aimed to use cyanate-esters, bismaleimides, benzoxazines matrices in combination with ex-PAN-CFs, ex-Rayon-CFs, and ex-Pitch-CFs. In our paper, after covering the science and technology of these state-of-the-art fiber reinforced TPS materials, a review of current challenges behind the manufacturing of new, high char yield matrices and carbon fibers derived from alternative precursors will be provided to the reader. In particular, the possibility to produce CFs from precursors different from PAN, Rayon and Pitch will be reported and similarly, the technology of non-oil based phenolics, bismaleimides, cyanate-esters and benzoxazines will be discussed. The effect of the use of nanosized fillers on these matrices will also be reported. More in detail, after a preliminary section in which the state of the art of technologies behind carbon/phenolic composites will be covered, a second part of this review paper will be focused on the most recent development related to non-oil based phenolics and biomass derived carbon fibers. Finally, an outlook focused on the maturity of the lab-scale protocols behind the researches at the base of these non-traditional raw materials from an industrial point of view will conclude this review paper.

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“…Once the temperature became higher than 150 • C, the system reached the rubber zone and the storage modulus of the composites tended to reach a stable state at low values. When the content of modified HGM was low, the composites showed a reduced storage modulus because of the interruption effect of modified HGM in the network, reducing the network density of the composites [34]. However, as the content of the modified HGM became greater than 10 wt %, the large amount of inorganic rigid particles resulted in considerable material rigidity in the low-temperature glass region, increasing the corresponding storage modulus [35].…”

Section: Thermal Properties Of the Compositesmentioning

confidence: 99%

Preparation and Characterization of Furan–Matrix Composites Blended with Modified Hollow Glass Microsphere

Zhao

et al. 2020

Polymers

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In this study, a new class of thermal insulation composites was prepared by blending a modified hollow glass microsphere (HGM) with furan resin. The particle dispersion between the microparticles and resin matrix was improved using 3-methacryloxypropyltrimethoxy silane (KH-570). Furthermore, the structure and morphology of the modified HGM were characterised by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). In addition, the effects of the modified HGM on the thermal insulation, flame retardancy, and thermal properties of the composites were investigated. The thermal conductivity of the composites was lower than that of the native furan resin. The minimum thermal conductivity of the composites was 0.0274 W/m·K; the flame retardancy of the composites improved, and the limiting oxygen index become a maximum of 31.6%, reaching the refractory material level. Furthermore, the thermal analysis of the composites demonstrated enhanced thermal stability. This study demonstrates that the composite material exhibited good thermal insulation performance and flame retardancy and that it can be applied in the field of thermal insulation.

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Bio-resourced furan resin as a sustainable alternative to petroleum-based phenolic resin for making GFR polymer composites

Cited by 18 publications

References 44 publications

Recent advances in the development of green furan ring-containing polymeric materials based on renewable plant biomass

Recent advances in the development of green furan ring-containing polymeric materials based on renewable plant biomass

High Temperature Composites From Renewable Resources: A Perspective on Current Technological Challenges for the Manufacturing of Non-Oil Based High Char Yield Matrices and Carbon Fibers

Preparation and Characterization of Furan–Matrix Composites Blended with Modified Hollow Glass Microsphere

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