“…(2012). Several mechanisms have been reported to explain the N 2 O emission reductions in biochar‐amended soils including: (1) increased adsorption of NO 3 (Singh et al., 2010; Van Zwieten et al., 2010), (2) improved soil physiochemical properties such as better soil aeration, constraining the activity of denitrifiers (Arif et al., 2020; van Zwieten et al., 2010), (3) decreased organic substrates availability to soil microorganisms (He et al., 2021; Kraus et al., 2018; Zhang et al., 2021), resulting in lower activity by denitrifying (Wang, Yang, et al., 2020) and ammonia oxidizing bacteria (Liu et al., 2014), (4) increased soil pH, making conditions more suitable for microbial respiration (van Zwieten et al., 2014) and N 2 O reductase (Van Zwieten et al., 2010), thus a lower amount of N 2 O in the N gas products, (5) inhibition of N transformation processes at the nitrification stage (Zhang, Bian, et al., 2012, Zhang, Liu, et al., 2012; Das et al., 2014), (6) enhanced the immobilization of mineral N by soil microbes due to the high C:N ratio of biochar, (7) increased adsorption of N 2 O on biochar due to large surface area of biochar (He et al., 2019; Lentz et al., 2014), and (8) presence of inhibitory substances such as ethylene that suppress soil microbial activity (Spokas et al., 2010). Nitrogen fertilizers and organic amendments are known to stimulate N 2 O emissions from soils (Aliyu et al., 2021; Charles et al., 2017).…”