“…Bioenergy production from waste streams can lead to the reduction of pollution, but also decrease the cost of their treatment. Among the new environmental friendly technologies, microbial bioelectrochemical systems (BESs), like microbial fuel cell (MFC) [1] or microbial electrolysis cell (MEC) [2], are considered one of the best alternatives for the sustainable waste treatment of contaminated groundwater [3], wastewater [4] and air polluted streams, and the concomitant production of energy or added value chemicals. [5] One of the critical challenges of these systems is to improve the interaction electrode-microorganism to ensure an effective transfer of electrons between the solid-state electrode and the biocatalyst.…”