Bioinspired interface engineering of soybean meal-based adhesive incorporated with biomineralized cellulose nanofibrils and a functional aminoclay

Kuang, Li; Jin, Shicun; Li, Xiaona; Li, Jiongjiong; Shi, Sheldon Q.; Li, Jianzhang

doi:10.1016/j.cej.2021.129820

Cited by 66 publications

(25 citation statements)

References 45 publications

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“…It is noted that nanofillers can serve as the physical filling phase, which could repair the discontinuous adhesion layer and form a stable and dense crosslinking structure. [93,94,95] Inorganic nanoparticles, such as montmorillonite (MMT), [39,40,96] montmorillonite clay (MMC), [97] kaolin (KL), [98] aminoclay (AC), [99,100] hydroxylapatite (HA), [101] nano-silica (SiO 2 ), [102] and carbon nanotube (CNT), [103] are widely used as the stiff skeletal phase to be introduced into the protein matrix to enhance the performance of wood adhesives. Also, functionalized mineral particles can act as a crosslinker to enhance the interactions with protein matrix, [104] and the mechanical performances of the composites are improved when the mineralization sites are generated in situ in soft organic network.…”

Section: Organic-inorganic Hybridmentioning

confidence: 99%

“…The cohesive strength of the resultant adhesive was increased due to the synergistic effect of sacrificial hydrogen bonds and multiple covalent bonds (Figure 9A). [99] The protein adhesive showed good flame retardancy and antimicrobial properties by constructing a positively charged surface of MCF/LAQ@AC and biomineralized structure (Figure 9B,C). [99] HA andTA complex as a rigid nanofiller and TGA as a crosslinking agent were applied to enhance the performance of the protein adhesive.…”

Section: Organic-inorganic Hybridmentioning

confidence: 99%

“…[99] The protein adhesive showed good flame retardancy and antimicrobial properties by constructing a positively charged surface of MCF/LAQ@AC and biomineralized structure (Figure 9B,C). [99] HA andTA complex as a rigid nanofiller and TGA as a crosslinking agent were applied to enhance the performance of the protein adhesive. It showed that the presence of hydrogen bonds and coordination bonds between TA@HA and protein matrix could increase the adhesion strength of the adhesive and effectively dissipate the energy to improve the toughness, preventing the formation of cracks [99] Copyright 2021, Elsevier.…”

Section: Organic-inorganic Hybridmentioning

confidence: 99%

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Developments in Bio‐Based Soy Protein Adhesives: A Review

Chen

Shi

Zhou

et al. 2022

Macro Materials & Eng

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Recently, soy protein has attracted extensive attention from wood industries and consumers in the production of wood adhesives as it is non‐toxic, biodegradable, low cost, and easy to process. There are a variety of reactive groups namely OH, NH2, COOH, and SH, in protein molecules, which offer possibilities for protein denaturation, chemical modification, and increased ionic interactions. The research in protein denaturation, crosslinking modification, biomimetic modification, and organic–inorganic hybrid formulation not only focuses on enhancing the mechanical properties and tolerance to water of the adhesives but also considers its toughness, mildew resistance, and flame retardancy to further optimize the performances of the adhesives. In this paper, soy protein chemical composition, soy protein denaturation, and reinforced modification are discussed to understand these methods and further develop into a multifunctional soy protein‐based adhesive. Given the potential of bio‐based adhesives, these modification methods not only provide the theoretical basis for its development at full scale, but also the possibility for the multifunctional applications of bio‐based adhesives.

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Section: Organic-inorganic Hybridmentioning

confidence: 99%

Section: Organic-inorganic Hybridmentioning

confidence: 99%

Section: Organic-inorganic Hybridmentioning

confidence: 99%

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Developments in Bio‐Based Soy Protein Adhesives: A Review

Chen

Shi

Zhou

et al. 2022

Macro Materials & Eng

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“…In order to realize the practical application of HPM adhesives, the structure and properties of natural proteins must be modified to improve their reactivity [ 12 ]. Common strategies used in previous reports include denaturation [ 13 ], crosslinking [ 14 ], and nano-material modification [ 15 ]. However, there have been no reports on the effects of different denaturation methods on the properties of HPM adhesive.…”

Section: Introductionmentioning

confidence: 99%

Effects of Different Denaturants on the Properties of a Hot-Pressed Peanut Meal-Based Adhesive

Guo

et al. 2022

Molecules

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Plant protein-based adhesives could fundamentally solve the problem of formaldehyde-based adhesive releasing formaldehyde, but enhancing bonding strength and water resistance is a necessary measure to realize practical applications. In this study, the effects of different denaturants on the properties of a hot-pressed peanut meal (HPM)-based adhesive before and after crosslinking were studied. Papain, sodium dodecyl sulfate (SDS), urea and crosslinker-polyamide epichlorohydrin (PAE) were used to prepare HPM-based adhesives. The functional groups, bonding strength, thermal behaviors, mass loss, moisture uptake value, viscosity and fracture surface of adhesive samples were analyzed. As a result, (1) papain was used to break HPM protein (HPMP) into polypeptide chains and to reduce the water resistance. (2) SDS and urea unfold the HPMP molecule and expose internal hydrophobic groups to improve the water resistance of the adhesive. (3) A denser network structure was formed by PAE and HPMP molecules, which significantly improved the bonding strength and water resistance of adhesives. In particular, after SDS denaturation and PAE crosslinking, compared with pure HPM adhesive, the wet shear strength increased by 96.4%, the mass loss and moisture uptake value reduced by 41.4% and 69.4%, and viscosity increased by 30.4%. This work provided an essential guide to design and prepare HPM-based adhesives.

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“…For instance, the properties of the bacterial nanocelluloses are based on different bacterial sources, whereas the properties of the cellulose nanocrystals and nanofibrillated celluloses are based on sources such as tunicin or plants [26]. Nanocellulose has garnered significant research interest as a promising nanomaterial that can revolutionise multiple fields, such as the pharmaceutical field [27], engineering [28], electronics [29] and health and environmental protection [30].…”

Section: Introductionmentioning

confidence: 99%

Preparation, Marriage Chemistry and Applications of Graphene Quantum Dots–Nanocellulose Composite: A Brief Review

2021

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Graphene quantum dots (GQDs) are zero-dimensional carbon-based materials, while nanocellulose is a nanomaterial that can be derived from naturally occurring cellulose polymers or renewable biomass resources. The unique geometrical, biocompatible and biodegradable properties of both these remarkable nanomaterials have caught the attention of the scientific community in terms of fundamental research aimed at advancing technology. This study reviews the preparation, marriage chemistry and applications of GQDs–nanocellulose composites. The preparation of these composites can be achieved via rapid and simple solution mixing containing known concentration of nanomaterial with a pre-defined composition ratio in a neutral pH medium. They can also be incorporated into other matrices or drop-casted onto substrates, depending on the intended application. Additionally, combining GQDs and nanocellulose has proven to impart new hybrid nanomaterials with excellent performance as well as surface functionality and, therefore, a plethora of applications. Potential applications for GQDs–nanocellulose composites include sensing or, for analytical purposes, injectable 3D printing materials, supercapacitors and light-emitting diodes. This review unlocks windows of research opportunities for GQDs–nanocellulose composites and pave the way for the synthesis and application of more innovative hybrid nanomaterials.

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Bioinspired interface engineering of soybean meal-based adhesive incorporated with biomineralized cellulose nanofibrils and a functional aminoclay

Cited by 66 publications

References 45 publications

Developments in Bio‐Based Soy Protein Adhesives: A Review

Developments in Bio‐Based Soy Protein Adhesives: A Review

Effects of Different Denaturants on the Properties of a Hot-Pressed Peanut Meal-Based Adhesive

Preparation, Marriage Chemistry and Applications of Graphene Quantum Dots–Nanocellulose Composite: A Brief Review

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