“…Similarly, compounds 10 and 11 (pseudomolecular ions [M−H] − at m/z 865), could be assigned to Btype (epi)catechin trimers. In all instances, the fragmentation patterns were consistent with those expected for such types of compounds, i.e., similar to those observed for proanthocyanidins dimers but with Proanthocyanidins and biflavonoids have been previously described as the most abundant compounds in A. angustifolia (Freitas et al, 2009;Peralta et al, 2016;da Silva et al, 2014;Yamaguchi, Kato, & Di, 2009;Yamaguchi, Vassa, Kato, & Mascio, 2005). Nevertheless, to the best of our knowledge, a detailed characterization of the proanthocyanidin fraction in A. angustifolia seeds has not been previously described.…”