Biomass-Derived Porous Carbon Materials for Li-Ion Battery

Нажипкызы, М.; Maltay, Anar B.; Askaruly, Kydyr; Assylkhanova, Dana D.; Seitkazinova, Aigerim R.; Mansurov, Zulkhair A.

doi:10.3390/nano12203710

Cited by 19 publications

(9 citation statements)

References 37 publications

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“…The BET specific surface area and porosity most likely do not have strong effect on this difference because of low variation range. Thus, other studies have shown that significant effect of specific surface area takes place only between ~100 and ~800 m 2 g −1 , while further increasing of specific surface area does not really affect [82–84] …”

Section: Resultsmentioning

confidence: 84%

“…Thus, other studies have shown that significant effect of specific surface area takes place only between ~100 and ~800 m 2 g À 1 , while further increasing of specific surface area does not really affect. [82][83][84] The analysis become even more complicated in case of Si and P. On one hand, the theoretical specific capacity of silicon is ~10 times higher than that of graphite. On the other hands, the cyclic stability is poor for both Si and SiO 2 showing fast degradation during first 2-7 cycles.…”

Section: Electrochemical Measurementsmentioning

confidence: 99%

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The effect of the pyrolysis temperature and biomass type on the biocarbons characteristics

Iurchenkova,

Kobets,

Ahaliabadeh

et al. 2024

ChemSusChem

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The conversion of biomass and natural wastes into carbon‐based materials for various applications such as catalysts and energy‐related materials is a fascinating and sustainable approach emerged during recent years. Precursor nature and characteristics are complex, hence, their effect on the properties of resulting materials is still unclear. In this work, we have investigated the effect of different precursors and pyrolysis temperature on the properties of produced carbon materials and their potential application as negative electrode materials in Li‐ion batteries. Three biomasses, lignocellulosic brewery spent grain from a local brewery, catechol‐rich lignin and tannins, were selected for investigations. We show that such end‐product carbon characteristic as functional and elemental composition, porosity, specific surface area, defectiveness level, and morphology strictly depend on the precursor composition, chemical structure, and pyrolysis temperature. The electrochemical characteristics of produced carbon materials are correlate with the characteristics of the produced materials. A higher pyrolysis temperature is shown to be favourable for production of carbon material for the Li‐ion battery application in terms of both specific surface area and long‐term cycling stability.

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Section: Resultsmentioning

confidence: 84%

Section: Electrochemical Measurementsmentioning

confidence: 99%

The effect of the pyrolysis temperature and biomass type on the biocarbons characteristics

Iurchenkova,

Kobets,

Ahaliabadeh

et al. 2024

ChemSusChem

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“…Biomass-derived carbon materials, readily available and abundant, are expected to allow the fabrication of large-scale thermocell for practical applications. In recent years, porous carbon materials derived from biomass waste have gained considerable attention as capacitors [26][27][28][29][30][31][32][33], batteries [34][35][36][37], and adsorbents [38,39] owing to low cost, eco-friendliness, and sustainability. Agricultural biomasses such as peanut shell [32], walnut shell [31], orange peel [27,33], jujube [28], tea waste [29], coffee waste [40], bagasse [30,34], leaf [38], and cone [26] have been proposed as sustainable sources for synthesizing hierarchical porous carbons.…”

Section: Preparation Of Cmp and Amp From Mandarin Peel Wastementioning

confidence: 99%

Biomass-Derived Sustainable Electrode Material for Low-Grade Heat Harvesting

Park

Kim

2023

Nanomaterials

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The ever-increasing energy demand and global warming caused by fossil fuels push for the exploration of sustainable and eco-friendly energy sources. Waste thermal energy has been considered as one of the promising candidates for sustainable power generation as it is abundantly available everywhere in our daily lives. Recently, thermo-electrochemical cells based on the temperature-dependent redox potential have been intensely studied for efficiently harnessing low-grade waste heat. Despite considerable progress in improving thermocell performance, no attempt was made to develop electrode materials from renewable precursors. In this work, we report the synthesis of a porous carbon electrode from mandarin peel waste through carbonization and activation processes. The influence of carbonization temperature and activating agent/carbon precursor ratio on the performance of thermocell was studied to optimize the microstructure and elemental composition of electrode materials. Due to its well-developed pore structure and nitrogen doping, the mandarin peel-derived electrodes carbonized at 800 °C delivered the maximum power density. The areal power density (P) of 193.4 mW m−2 and P/(ΔT)2 of 0.236 mW m−2 K−2 were achieved at ΔT of 28.6 K. However, KOH-activated electrodes showed no performance enhancement regardless of activating agent/carbon precursor ratio. The electrode material developed here worked well under different temperature differences, proving its feasibility in harvesting electrical energy from various types of waste heat sources.

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“…6−10 These are potential sustainable sources of carbon for energy storage applications; however, most of these are obtained by multistep processes needing elaborate conditioning and postprocessing such as the need for acid/ base treatments before pyrolysis, addition of activators, 11,12 and/or high-temperature treatment (>1000 °C). 13 Also, capacity fading is observed over time, which results in poor cyclability.…”

Section: ■ Introductionmentioning

confidence: 99%

“…It is beyond doubt that the progressive growth will lead to enhanced energy demand, and there shall be an urgent need for cost-effective materials with higher energy density. To this effect, different disordered carbons obtained from biomass have been explored as anode materials for LIBs for better storage capacity. − These are potential sustainable sources of carbon for energy storage applications; however, most of these are obtained by multistep processes needing elaborate conditioning and postprocessing such as the need for acid/base treatments before pyrolysis, addition of activators, , and/or high-temperature treatment (>1000 °C) . Also, capacity fading is observed over time, which results in poor cyclability.…”

Section: Introductionmentioning

confidence: 99%

Carbon–Manganese Oxide Composite Derived from Wheat Flour: Kitchen-Inspired Green Synthesis and Applications in Energy Storage

Dutta Pathak,

Guleria,

Nuwad

et al. 2024

ACS Appl. Electron. Mater.

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The quest for better alternatives for graphite anodes is the holy grail in the field of energy storage technologies. Biomass-derived carbon has been widely explored as the energydense and cost-effective option but involves several pre/postconditioning steps. In this study, kitchen chemistry concepts of fermentation have been utilized to obtain sustainable carbon anodes from readily available and cost-effective wheat flour and baker's yeast. The yeast-fermented mixture of wheat flour and MnCO 3 is pyrolyzed under 500 °C to yield porous C-MnO composites, which have been explored as an anode for Li-ion batteries. The material showed superior electrochemical performance with an initial discharge of 1160 mAh g −1 at 0.15 A g −1 (after solid electrolyte interface formation). A reversible capacity of 1499 mAh g −1 was obtained with a concomitant improvement of 30% after 160 cycles exhibiting a "negative fading effect". Excellent electrochemical behavior has been attributed to the synergistic effect of in situ synthesized, well-dispersed MnO in carbon, the presence of redox-active Mn, and well-connected porosity in nanohybrids. At a high current density of 1 A g −1 , the anode displayed an exemplary initial discharge capacity of 770 mAh g −1 with a high initial Coulombic efficiency of 90%, which was maintained at 856 mAh g −1 after 760 cycles. Easy synthesis and excellent electrochemical performance render this material highly promising for battery applications.

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Biomass-Derived Porous Carbon Materials for Li-Ion Battery

Cited by 19 publications

References 37 publications

The effect of the pyrolysis temperature and biomass type on the biocarbons characteristics

The effect of the pyrolysis temperature and biomass type on the biocarbons characteristics

Biomass-Derived Sustainable Electrode Material for Low-Grade Heat Harvesting

Carbon–Manganese Oxide Composite Derived from Wheat Flour: Kitchen-Inspired Green Synthesis and Applications in Energy Storage

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