interactions of weak van der Waals force to form thick graphene-based film, and the films are not strong enough to withstand tensile and compression due to weak connection. [1] Past efforts in solving this problem were focused on improving the strength of graphene-based films through incorporating a polymer as a binder. [2][3][4] While this strategy has helped improve the mechanical performance of graphene-based films, it leads to the deterioration of other properties, such as thermal properties. The use of polymer binders greatly reduces the thermal conductivity of graphene-based film due to the low thermal conductivity of polymers and the high inherent interfacial thermal resistance between graphene and polymers. [5,6] To improve the thermal conductivity of graphene-based films, one effective solution is to incorporate polymers with high intrinsic thermal conductivity, [7] but the improvement is limited to a certain level.In order to generate graphene-based systems with high thermal conductivity, graphene films can be used as casing materials to prepare a two-phase heat transport device (TPHTD). Such a device mainly relies on the phase change heat transfer process and takes advantage of both the large latent heat and the fast flow of the vapor from the evaporator to the condenser to realize efficient heat transfer, thus achieving high thermal conductivity, enabling its extensive use in thermal management devices. [8][9][10] So far, graphene has been used in two different ways for the TPHTD. In one way, graphene is coated on the inner wall of the metal-based casing in the TPHTD. [11][12][13][14] While this approach improves the thermal conductivity of the TPHTD due to good-wettability and low flow resistance of working medium on the surface of graphene, the resulting device is still heavy due to the metal-based casing, which does not take advantage of the lightweight property of graphene. The other is to use graphene as the casing material and metal frame as the support to prepare TPHTDs. [15] Such an approach still has not yet been realized to lightweight all graphene-based TPHTDs. To achieve all graphene-based TPHTDs with high thermal performance, an alternative approach is needed to form reliable binding between graphene nanosheets at nanoscale and achieve desired geometry of devices at macroscale. Graphene-based composites show great potential in the development of lightweight functional devices and systems, and polymers are usually used as binders to enhance the mechanical properties of these composites. Due to the low thermal conductivity of the polymer and the high inherent interfacial thermal resistance between polymer and graphene, however, the developed devices and systems generally possess low thermal conductivity, which seriously limits their further thermal-related applications. Here, a lightweight two-phase heat transport device (TPHTD) based on a vapor-liquid phase transition-based heat transfer by using a graphene-based composite material as the casing is generated. The graphene-based TPHTD has h...