Biopolymers
and alkali-activated materials have attracted a great
deal of attention as adsorbents for the removal of heavy metal contaminants
from aqueous solutions. Both materials are sustainable and feature
unique properties, but biopolymers are relatively more expensive or
difficult to prepare and exhibit low mechanical and surface properties,
a narrow pH range, and thermal stability. In this study, hybrid adsorbents
were prepared from both types of material, by alkali activation of
low-cost fly ash precursors accompanied by incorporation of 0–2%mass chitosan biopolymer. Two types of alkaline activating
solutions, NaOH and Na2SiO3, were employed to
generate two sets of hybrid adsorbents with varying chitosan contents.
The effect of the chitosan dosage on the aqueous Pb(II) and Zn(II)
sorption efficiency was also investigated. The adsorbents exhibited
98–100% removal efficiencies for both metals, but the sorption
of Zn(II) was generally higher than that of Pb(II). The addition of
0.1–2.0%mass chitosan resulted in very little improvement
in the overall efficiency of the adsorbents. In contrast, 0.05%mass chitosan led to a decrease in the sorption efficiency;
this was linked to the decrease in the adsorbents’ ζ
potential. The Na2SiO3-activated materials featured
larger BET surface areas and better overall sorption performance,
while the NaOH-activated materials showed the worst Pb(II) sorption
performance and hence more noticeable improvement upon addition of
chitosan. Mechanistic investigation shows that the sorption process
follows second-order kinetics and is a chemisorption-driven process.