Subcritical water hydrolysis and lipase-catalyzed hydrolysis
(SWH
and LPH, respectively) emerge as promising methods for hydrolyzing
triglycerides to fatty acids. In this work, technoeconomic and environmental
aspects of the two methods, using palm oil splitting as a model, at
plant capacities of 10–200 tons/day have been investigated.
While the annual operating costs of the two methods are comparable,
SWH incurs significantly higher capital investment than LPH. As a
result, the minimum selling price (MSP) of fatty acids for SWH is
higher than that for LPH across all plant capacities studied. For
the 10 tons/day capacity, the MSP values for SWH and LPH are 1.143
and 1.019 USD/kg, respectively. Heat integration is recommended so
as to lower the MSP for SWH. Both alternative oil sources and longer
lipase operational lifetime are important to the process economics.
Finally, a cradle-to-gate life-cycle assessment clearly suggests that
LPH is more environmentally friendly than SWH in all impact categories.
The impacts of different life-cycle stages and use of sludge oils
are also discussed.