Biotransformation of dicarboxylic acids from vegetable oil–derived sources: current methods and suggestions for improvement

Lee, Heeseok; Sugiharto, Yohanes Eko Chandra; Lee, Hyeok-Won; Jeon, Wooyoung; Ahn, Jungoh

doi:10.1007/s00253-018-9571-7

Cited by 23 publications

(23 citation statements)

References 89 publications

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“…These dicarboxylic acids impart high impact strength, hydrolytic stability, hydrophobicity, lower glass transition temperatures, and flexibility to the final materials [18]. In addition, technologies for the commercialization of other dicarboxylic acids derived from vegetable oils, such as adipic acid and dodecanedioic acid, are currently under development by some companies [21].…”

Section: Introductionmentioning

confidence: 99%

The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources

et al. 2021

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This paper provides an overview of the recent progress in research and development dealing with polymers derived from plant oils. It highlights the widening interest in novel approaches to the synthesis, characterization, and properties of these materials from renewable resources and emphasizes their growing impact on sustainable macromolecular science and technology. The monomers used include unmodified triglycerides, their fatty acids or the corresponding esters, and chemically modified triglycerides and fatty acid esters. Comonomers include styrene, divinylbenzene, acrylics, furan derivatives, epoxides, etc. The synthetic pathways adopted for the preparation of these materials are very varied, going from traditional free radical and cationic polymerizations to polycondensation reactions, as well as metatheses and Diels–Alder syntheses. In addition to this general appraisal, the specific topic of the use of tung oil as a source of original polymers, copolymers, and (nano)composites is discussed in greater detail in terms of mechanisms, structures, properties, and possible applications.

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Section: Introductionmentioning

confidence: 99%

The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources

et al. 2021

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“…Aliphatic α,ω‐dicarboxylic acids (DCAs) are a class of chemicals extensively used in the preparation of perfumes, polymers, adhesives, and macrolide antibiotics 1 , 2 . Currently, the majority of industrial DCAs are synthesized by energy-intensive, hazardous multistage oxidations.…”

Section: Introductionmentioning

confidence: 99%

One-pot biocatalytic route from cycloalkanes to α,ω‐dicarboxylic acids by designed Escherichia coli consortia

Wang

Zhao

et al. 2020

Nat Commun

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Aliphatic α,ω‐dicarboxylic acids (DCAs) are a class of useful chemicals that are currently produced by energy-intensive, multistage chemical oxidations that are hazardous to the environment. Therefore, the development of environmentally friendly, safe, neutral routes to DCAs is important. We report an in vivo artificially designed biocatalytic cascade process for biotransformation of cycloalkanes to DCAs. To reduce protein expression burden and redox constraints caused by multi-enzyme expression in a single microbe, the biocatalytic pathway is divided into three basic Escherichia coli cell modules. The modules possess either redox-neutral or redox-regeneration systems and are combined to form E. coli consortia for use in biotransformations. The designed consortia of E. coli containing the modules efficiently convert cycloalkanes or cycloalkanols to DCAs without addition of exogenous coenzymes. Thus, this developed biocatalytic process provides a promising alternative to the current industrial process for manufacturing DCAs.

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“…In literature, several substrates have been investigated for the production of long-chain DCA ranging from alkanes, fatty acids, fatty acid esters, fatty alcohols and vegetable oils [2,[19][20][21] Most of these substrates are already valuable because they are pure chemicals derived from vegetable oil and can be applied in other production processes, e.g. food additives, pharmaceuticals, etc.…”

Section: Introductionmentioning

confidence: 99%

Chocolate industry side streams as a valuable feedstock for microbial long-chain dicarboxylic acid production

Bauwelinck

Caluwé

Wijnants

et al. 2021

Biochemical Engineering Journal

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Biotransformation of dicarboxylic acids from vegetable oil–derived sources: current methods and suggestions for improvement

Cited by 23 publications

References 89 publications

The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources

The Prospering of Macromolecular Materials Based on Plant Oils within the Blooming Field of Polymers from Renewable Resources

One-pot biocatalytic route from cycloalkanes to α,ω‐dicarboxylic acids by designed Escherichia coli consortia

Chocolate industry side streams as a valuable feedstock for microbial long-chain dicarboxylic acid production

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