For arbitrary semimetric space (X, d) and disjoint proximinal subsets A, B of X we define the proximinal graph as the bipartite graph with parts A and B whose edges {a, b} satisfy the equality d(a, b) = dist(A, B). The structure of proximinal graphs is completely described for strongly rigid semimetric spaces. It is shown that a graph G is not isomorphic to any proximinal graph of any strongly rigid semimetric space iff either G is a finite null graph or satisfies at least one from the inequalities |E(G)| > 1 and |V (G)| > c, where c is the cardinality of the continuum. We also characterize all semimetric spaces for which every proximinal graph has at most one edge and all semimetric spaces for which every point has exactly one best approximation in each proximinal set.