Bismuth(III) dimethyldithioarsinate, Bi(S2AsMe2)3: A new dimer formed through Bi ? S secondary bonding

Cea‐Olivares, Raymundo; Ebert, K. H.; Silaghi‐Dumitrescu, Luminiţa; Haiduc, Ionel

doi:10.1002/(sici)1098-1071(1997)8:4<317::aid-hc5>3.0.co;2-7

Cited by 11 publications

(2 citation statements)

References 18 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The crystal structures of LK · 2H 2 O 16, L 3 Bi 17, L 3 In 18, L 3 Cr 19, Ph 2 SbL 20 and Me 2 SnL 2 21 were reported as well as the solid state IR spectra 8 and magnetic properties 9 of some complexes. Bunsen studied the thermal behavior and the chemical properties of some complexes 5, and we continued these investigations in an earlier publication 7.…”

Section: Introductionmentioning

confidence: 99%

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me₂AsS₂Na·2H₂O, and Palladium(II) Dimethyldithioarsinate, (Me₂AsS₂)₂Pd

Ioannou

Vachliotis

Nastopoulos

et al. 2009

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

Section: Introductionmentioning

confidence: 99%

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me₂AsS₂Na·2H₂O, and Palladium(II) Dimethyldithioarsinate, (Me₂AsS₂)₂Pd

Ioannou

Vachliotis

Nastopoulos

et al. 2009

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

“…The S–As–S angles of the two bridging ligands, 116.9° and 117.2°, are quite bigger than the corresponding angles in the octahedral complexes (Me 2 AsS 2 ) 3 In14 and (Me 2 AsS 2 ) 3 Cr,19 which are in the range of 104.6–107.1° and 101.4–103.1°, respectively. The bismuth(III) complex (Me 2 AsS 2 ) 3 Bi, in which the ligands are arranged in a pentagonal pyramidal arrangement around Bi III ,20 being dimeric and having a Bi ···· S bond, is not directly comparable with 2 .…”

Section: Resultsmentioning

confidence: 99%

The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me₂AsS₂)₂Ga]₂S·0.75H₂O: A Hydrolysis Product of (Me₂AsS₂)₃Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

Papatriantafyllopoulou

Nastopoulos

Ioannou

2014

Zeitschrift anorg allge chemie

View full text Add to dashboard Cite

The complex (Me 2 AsS 2 ) 3 Ga (1) attracted water molecules that slowly and completely hydrolyzed it. The product was the dinuclear gallium compound (Me 2 AsS 2 ) 2 Ga-S-Ga(S 2 AsMe 2 ) 2 (2) as 2·0.75H 2 O, which was structurally characterized with X-ray crystallography (P2 1 2 1 2 1 , R 1 = 0.0321, wR 2 = 0.0622). Compound 2 shows * Prof. Dr. P. V. Ioannou E-Mail: ioannou@chemistry.upatras.gr [a] 1654 an approximate non-crystallographic twofold axis. The packing in the crystalline state is dictated by the mediation of crystallization water molecules, which connect the complex units through strong O-H···S and weak C-H···O hydrogen bonds into infinite zigzag chains.Having the gallium complex (Me 2 AsS 2 ) 3 Ga (1), we tried to crystallize it in order to see whether the arrangement around gallium is the same as in (Me 2 AsS 2 ) 3 In [14] or is different as in the case of [(Me 2 CHCH 2 ) 2 PS 2 ] 3 M, in which for M = Ga the arrangement is tetrahedral, and for M = In the arrangement is octahedral. [6] However, the crystals isolated were due to the new and novel complex 2 described herein.

show abstract

Supramolecular Self‐Assembly by Formation of Secondary Bonds

Haiduc

Edelmann

1999

Supramolecular Organometallic Chemistry

View full text Add to dashboard Cite

Bismuth(III) dimethyldithioarsinate, Bi(S2AsMe2)3: A new dimer formed through Bi ? S secondary bonding

Cited by 11 publications

References 18 publications

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me₂AsS₂Na·2H₂O, and Palladium(II) Dimethyldithioarsinate, (Me₂AsS₂)₂Pd

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me₂AsS₂Na·2H₂O, and Palladium(II) Dimethyldithioarsinate, (Me₂AsS₂)₂Pd

The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me₂AsS₂)₂Ga]₂S·0.75H₂O: A Hydrolysis Product of (Me₂AsS₂)₃Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

Supramolecular Self‐Assembly by Formation of Secondary Bonds

Contact Info

Product

Resources

About

Bismuth(III) dimethyldithioarsinate, Bi(S2AsMe2)3: A new dimer formed through Bi ? S secondary bonding

Cited by 11 publications

References 18 publications

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me2AsS2Na·2H2O, and Palladium(II) Dimethyldithioarsinate, (Me2AsS2)2Pd

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me2AsS2Na·2H2O, and Palladium(II) Dimethyldithioarsinate, (Me2AsS2)2Pd

The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me2AsS2)2Ga]2S·0.75H2O: A Hydrolysis Product of (Me2AsS2)3Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands

Supramolecular Self‐Assembly by Formation of Secondary Bonds

Contact Info

Product

Resources

About

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me₂AsS₂Na·2H₂O, and Palladium(II) Dimethyldithioarsinate, (Me₂AsS₂)₂Pd

Preparation and Properties of Sodium Dimethyldithioarsinate Dihydrate, Me₂AsS₂Na·2H₂O, and Palladium(II) Dimethyldithioarsinate, (Me₂AsS₂)₂Pd

The Structure of Bis(dimethyldithioarsinato)gallium(III) Sulfide [(Me₂AsS₂)₂Ga]₂S·0.75H₂O: A Hydrolysis Product of (Me₂AsS₂)₃Ga that Contains a Bridging Sulfide and both Pendant and Bridging Dimethyldithioarsinato Ligands