Suppressed aggregation: The unprecedented alumoxane hydrogensulfide [{LAl(SH)}2(μ‐O)] and the unique sulfide‐bridged compound [{LAl(SH)}2(μ‐S)] can be prepared from the easily accessible aluminum dihydride [LAlH2] (L=HC[(CMe)N(2,4,6‐Me3C6H2)]2−). Owing to the cis conformation of the terminal SH groups, these compounds represent ideal precursors for the synthesis of heterometallic compounds.
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